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Surface Damage of PVC Polymers during XPS Analysis
https://doi.org/10.24517/00010401
https://doi.org/10.24517/000104015060dabd-9207-48a8-bcba-a7ad28bb2581
名前 / ファイル | ライセンス | アクション |
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SC-PR-ENO-K-9_471[1].pdf (407.2 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-10-03 | |||||
タイトル | ||||||
タイトル | Surface Damage of PVC Polymers during XPS Analysis | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
ID登録 | ||||||
ID登録 | 10.24517/00010401 | |||||
ID登録タイプ | JaLC | |||||
著者 |
Takaoka, K.
× Takaoka, K.× Koizumi, S.× Maeda, S.× Bureau, C.× Endo, Kazunaka× Hyodo, K.× Miura, H. |
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著者別表示 |
遠藤, 一央
× 遠藤, 一央 |
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提供者所属 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 金沢大学ナノマテリアル研究所 / 金沢大学理工研究域数物科学系 / 金沢大学大学院自然科学研究科物質情報解析 | |||||
書誌情報 |
Journal of Surface Analysis 巻 9, 号 3, p. 471-476, 発行日 2002-01-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1347-8400 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12022731 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1384/jsa.9.471 | |||||
出版者 | ||||||
出版者 | 表面分析研究会 = Surface Analysis Society of Japan | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | We examined surface damage for polyvinyl chloride (PVC) sample after 260 minutes at an unmonochromated Al Kα X-ray source power at 600 W, because PVC decomposes very quickly due to the X-ray irradiation. The pendant Cl groups of the PVC were estimated to cleave more rapidly than C-C bonds in the main chains from two-center bond energies calculated by AM1 method using the model pentamer. The valence XPS of the polymer at the initial time, and after 120 and 260 minutes of X-ray irradiation were analyzed by deMon density-functional theory (DFT) calculations using the model pentamer. The simulated results afforded us that the pendant Cl groups of PVC cleave mainly due to the X-ray radiation. | |||||
権利 | ||||||
権利情報 | Copyright (c) 2003 一般社団法人 表面分析研究会 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.sasj.jp/jpn-index.html | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://japanlinkcenter.org/JST.JSTAGE/jsa/9.471 |