WEKO3
インデックスリンク
アイテム
{"_buckets": {"deposit": "822f29d7-78e3-44d3-87f1-710460775561"}, "_deposit": {"created_by": 3, "id": "14779", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "14779"}, "status": "published"}, "_oai": {"id": "oai:kanazawa-u.repo.nii.ac.jp:00014779", "sets": ["1135"]}, "author_link": ["26437", "26369", "26438", "26436"], "item_4_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1990-05-25", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "1204", "bibliographicPageStart": "1200", "bibliographicVolumeNumber": "38", "bibliographic_titles": [{"bibliographic_title": "Chemical \u0026 pharmaceutical bulletin"}]}]}, "item_4_description_21": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The first total synthesis of ochropposinine (1), a Neisosperma and Ochrosia alkaloid, has been accomplished in the form of a racemic modification by means of an initial coupling of the lactim ether (±)-3 with 5 and succeeding steps proceeding through the intermediates (±)-7,(±)-8,(±)-9,(±)-10,and (±)-11. A parallel synthetic route starting with (+)-3 produced the chiral target molecule (-)-1 via the intermediates (+)-7,(+)-8,(+)-9,10,and (-)-11. As a result, the absolute configuration of ochropposinine has been unequivocally established to be that represented by formula (-)-1.", "subitem_description_type": "Abstract"}]}, "item_4_publisher_17": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "日本薬学会"}]}, "item_4_relation_12": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1248/cpb.38.1200", "subitem_relation_type_select": "DOI"}}]}, "item_4_source_id_11": {"attribute_name": "NCID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00602100", "subitem_source_identifier_type": "NCID"}]}, "item_4_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0009-2363", "subitem_source_identifier_type": "ISSN"}]}, "item_4_version_type_25": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Fujii, Tozo"}], "nameIdentifiers": [{"nameIdentifier": "26436", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ohba, Masashi"}], "nameIdentifiers": [{"nameIdentifier": "26369", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "60115219", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=60115219"}, {"nameIdentifier": "60115219", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000060115219"}]}, {"creatorNames": [{"creatorName": "Tachinami, Tsuyoshi"}], "nameIdentifiers": [{"nameIdentifier": "26437", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Miyajima, Hisae"}], "nameIdentifiers": [{"nameIdentifier": "26438", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-10-03"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "PE-PR-OHBA-M-1200.pdf", "filesize": [{"value": "951.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 951000.0, "url": {"label": "PE-PR-OHBA-M-1200.pdf", "url": "https://kanazawa-u.repo.nii.ac.jp/record/14779/files/PE-PR-OHBA-M-1200.pdf"}, "version_id": "5cdd8466-c9d6-42a6-a489-765a76042f3d"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Neisosperma alkaloid", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Ochrosia alkaloid", "subitem_subject_scheme": "Other"}, {"subitem_subject": "ochropposinine", "subitem_subject_scheme": "Other"}, {"subitem_subject": "indoloquinolizidine alkaloid synthesis", "subitem_subject_scheme": "Other"}, {"subitem_subject": "chiral synthesis", "subitem_subject_scheme": "Other"}, {"subitem_subject": "lactim ether alkylation", "subitem_subject_scheme": "Other"}, {"subitem_subject": "keto amide cyclization", "subitem_subject_scheme": "Other"}, {"subitem_subject": "oxazolium salt reduction", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Bischler-Napieralski cyclization", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hydride reduction", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Quinolizidines. XXVII. Racemic and chiral syntheses of the Neisosperma and Ochrosia alkaloid ochropposinine", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Quinolizidines. XXVII. Racemic and chiral syntheses of the Neisosperma and Ochrosia alkaloid ochropposinine"}]}, "item_type_id": "4", "owner": "3", "path": ["1135"], "permalink_uri": "http://hdl.handle.net/2297/7593", "pubdate": {"attribute_name": "公開日", "attribute_value": "2017-10-03"}, "publish_date": "2017-10-03", "publish_status": "0", "recid": "14779", "relation": {}, "relation_version_is_last": true, "title": ["Quinolizidines. XXVII. Racemic and chiral syntheses of the Neisosperma and Ochrosia alkaloid ochropposinine"], "weko_shared_id": 3}
Quinolizidines. XXVII. Racemic and chiral syntheses of the Neisosperma and Ochrosia alkaloid ochropposinine
http://hdl.handle.net/2297/7593
http://hdl.handle.net/2297/75932b5922cb-c60d-47ca-af54-7b0820b73980
名前 / ファイル | ライセンス | アクション |
---|---|---|
PE-PR-OHBA-M-1200.pdf (951.0 kB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2017-10-03 | |||||
タイトル | ||||||
タイトル | Quinolizidines. XXVII. Racemic and chiral syntheses of the Neisosperma and Ochrosia alkaloid ochropposinine | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Fujii, Tozo
× Fujii, Tozo× Ohba, Masashi× Tachinami, Tsuyoshi× Miyajima, Hisae |
|||||
書誌情報 |
Chemical & pharmaceutical bulletin 巻 38, 号 5, p. 1200-1204, 発行日 1990-05-25 |
|||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0009-2363 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00602100 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1248/cpb.38.1200 | |||||
出版者 | ||||||
出版者 | 日本薬学会 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The first total synthesis of ochropposinine (1), a Neisosperma and Ochrosia alkaloid, has been accomplished in the form of a racemic modification by means of an initial coupling of the lactim ether (±)-3 with 5 and succeeding steps proceeding through the intermediates (±)-7,(±)-8,(±)-9,(±)-10,and (±)-11. A parallel synthetic route starting with (+)-3 produced the chiral target molecule (-)-1 via the intermediates (+)-7,(+)-8,(+)-9,10,and (-)-11. As a result, the absolute configuration of ochropposinine has been unequivocally established to be that represented by formula (-)-1. | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |