WEKO3
インデックスリンク
アイテム
{"_buckets": {"deposit": "1e82f579-967d-4436-9c58-6b7acc18876d"}, "_deposit": {"created_by": 3, "id": "15414", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "15414"}, "status": "published"}, "_oai": {"id": "oai:kanazawa-u.repo.nii.ac.jp:00015414", "sets": ["1135"]}, "author_link": ["288", "28050"], "item_4_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1996-01-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "2", "bibliographicPageEnd": "274", "bibliographicPageStart": "261", "bibliographicVolumeNumber": "69", "bibliographic_titles": [{"bibliographic_title": "Bulletin of the Chemical Society of Japan"}]}]}, "item_4_description_21": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Orientation rules for photochemical nucleophilic substitutions are deduced from intramolecular photoreactions of some bichromophoric chain molecules, p-O2NC6H4O(CH2)nNHC6H5. The lower homologues undergo photochemical nucleophilic substitutions which can be classified as a Smiles-type photorearrangement. The photochemistry of this type of bifunctional chain species depends upon the methylene chain length. When the chain length is sufficiently long, the photorearrangement is totally forbidden. Photoredox reactions are the only accessible reaction processes for the higher homologues. The photoredox reaction consisting of cage and escape pathways is modulated by an external magnetic field. The magnetic field effects on the end product distribution are due to changes in the intersystem crossing rate induced by hyperfine interaction within biradical intermediates.", "subitem_description_type": "Abstract"}]}, "item_4_publisher_17": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "The Chemical Society of Japan = 日本化学会"}]}, "item_4_relation_12": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1246/bcsj.69.261", "subitem_relation_type_select": "DOI"}}]}, "item_4_relation_28": {"attribute_name": "関連URI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://www.jstage.jst.go.jp/browse/bcsj", "subitem_relation_type_select": "URI"}}, {"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://www.chemistry.or.jp/", "subitem_relation_type_select": "URI"}}]}, "item_4_rights_23": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright © The Chemical Society of Japan 日本化学会"}]}, "item_4_source_id_11": {"attribute_name": "NCID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00580132", "subitem_source_identifier_type": "NCID"}]}, "item_4_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0009-2673", "subitem_source_identifier_type": "ISSN"}]}, "item_4_version_type_25": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Nakagaki, Ryoichi"}], "nameIdentifiers": [{"nameIdentifier": "288", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "20159057", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=20159057"}, {"nameIdentifier": "20159057", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000020159057"}]}, {"creatorNames": [{"creatorName": "Mutai, Kiyoshi"}], "nameIdentifiers": [{"nameIdentifier": "28050", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-10-04"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "PH-PR-NAKAGAKI-R-261.pdf", "filesize": [{"value": "2.5 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2500000.0, "url": {"label": "PH-PR-NAKAGAKI-R-261.pdf", "url": "https://kanazawa-u.repo.nii.ac.jp/record/15414/files/PH-PR-NAKAGAKI-R-261.pdf"}, "version_id": "965275fe-0c71-4a76-bd14-65f3355f7e1b"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Photophysical properties and photosubstitution and photoredox reactions of aromatic nitro compounds", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Photophysical properties and photosubstitution and photoredox reactions of aromatic nitro compounds"}]}, "item_type_id": "4", "owner": "3", "path": ["1135"], "permalink_uri": "http://hdl.handle.net/2297/38253", "pubdate": {"attribute_name": "公開日", "attribute_value": "2017-10-04"}, "publish_date": "2017-10-04", "publish_status": "0", "recid": "15414", "relation": {}, "relation_version_is_last": true, "title": ["Photophysical properties and photosubstitution and photoredox reactions of aromatic nitro compounds"], "weko_shared_id": -1}
Photophysical properties and photosubstitution and photoredox reactions of aromatic nitro compounds
http://hdl.handle.net/2297/38253
http://hdl.handle.net/2297/382535dbc65c8-c366-4e54-ad8a-ff54ca83e6ae
名前 / ファイル | ライセンス | アクション |
---|---|---|
PH-PR-NAKAGAKI-R-261.pdf (2.5 MB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2017-10-04 | |||||
タイトル | ||||||
タイトル | Photophysical properties and photosubstitution and photoredox reactions of aromatic nitro compounds | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Nakagaki, Ryoichi
× Nakagaki, Ryoichi× Mutai, Kiyoshi |
|||||
書誌情報 |
Bulletin of the Chemical Society of Japan 巻 69, 号 2, p. 261-274, 発行日 1996-01-01 |
|||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0009-2673 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00580132 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1246/bcsj.69.261 | |||||
出版者 | ||||||
出版者 | The Chemical Society of Japan = 日本化学会 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Orientation rules for photochemical nucleophilic substitutions are deduced from intramolecular photoreactions of some bichromophoric chain molecules, p-O2NC6H4O(CH2)nNHC6H5. The lower homologues undergo photochemical nucleophilic substitutions which can be classified as a Smiles-type photorearrangement. The photochemistry of this type of bifunctional chain species depends upon the methylene chain length. When the chain length is sufficiently long, the photorearrangement is totally forbidden. Photoredox reactions are the only accessible reaction processes for the higher homologues. The photoredox reaction consisting of cage and escape pathways is modulated by an external magnetic field. The magnetic field effects on the end product distribution are due to changes in the intersystem crossing rate induced by hyperfine interaction within biradical intermediates. | |||||
権利 | ||||||
権利情報 | Copyright © The Chemical Society of Japan 日本化学会 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://www.jstage.jst.go.jp/browse/bcsj | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.chemistry.or.jp/ |