WEKO3
インデックスリンク
アイテム
{"_buckets": {"deposit": "69370fe2-c433-4159-913f-406dfc75aa3a"}, "_deposit": {"created_by": 3, "id": "31266", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "31266"}, "status": "published"}, "_oai": {"id": "oai:kanazawa-u.repo.nii.ac.jp:00031266", "sets": ["2276"]}, "author_link": ["15677", "53152", "53153"], "item_4_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1975-02-10", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "2", "bibliographicPageEnd": "120", "bibliographicPageStart": "116", "bibliographicVolumeNumber": "24", "bibliographic_titles": [{"bibliographic_title": "分析化学 = Japan analyst"}]}]}, "item_4_description_21": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "l00ml分液漏斗に1M塩化アンモニウム-アンモニア水溶液(pPH10) 50ml、水銀2・5mlを入れ、窒素ガスを通じ脱酸素してから、試料の高純度金属カドミウム片を加え振り混ぜると、金属はアマルガムとなって水銀中に溶解し、酸化物はアンミン錯イオンとなって水溶液中に溶ける。水銀を分離した後、水溶液についてカドミウムの量を原子吸光法で定量すれば酸化物を求められる。本法は精度は高く、金属表面及び内部の酸化物を分別的に定量できることにも特長がある。 In a 100ml separating funnel were added 50ml of 1M ammonium chloride-aqueous ammonia buffer solution(pH1O) and 2.5ml mercury; after passing nitrogen gag sufficiently to remove oxygen from the vessel and also from the aqueous solution, several pieces of cadmium metal of high purity were put into the vessel. The content was shaken vigorously; the metal went into mercury forming cadmium-amalgam, while the cadmium oxide dissolved itself in the aqueous solution to form cadmium tetrammine complex cations. After removal of mercury from the funnel, the solution was submitted to the determination of cadmium dissolved in it by means of the atomic absorption spectrophotometry or the EDTA titration. By the above procedure a minute amount of cadmium oxide could be determined precisely with high reproducibility. The critical experiments were also done to clarify the behaviors of cadmium metal and cadmium oxide in this separation process for the purpose of establishing a suitable procedure.", "subitem_description_type": "Abstract"}]}, "item_4_description_5": {"attribute_name": "提供者所属", "attribute_value_mlt": [{"subitem_description": "金沢大学イノベーション創成センター", "subitem_description_type": "Other"}]}, "item_4_publisher_17": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "The Japan Society for Analytical Chemistry = 日本分析化学会"}]}, "item_4_relation_28": {"attribute_name": "関連URI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://www.jsac.or.jp/index.html", "subitem_relation_type_select": "URI"}}, {"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://ci.nii.ac.jp/naid/110002907503/en/", "subitem_relation_type_select": "URI"}}]}, "item_4_rights_23": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "Copyright (c) 1975 日本分析化学会"}]}, "item_4_source_id_11": {"attribute_name": "NCID", "attribute_value_mlt": [{"subitem_source_identifier": "AN00222633", "subitem_source_identifier_type": "NCID"}]}, "item_4_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0525-1931", "subitem_source_identifier_type": "ISSN"}]}, "item_4_version_type_25": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "木羽, 敏泰"}], "nameIdentifiers": [{"nameIdentifier": "53152", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "松本, 健"}], "nameIdentifiers": [{"nameIdentifier": "15677", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "20110603", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=20110603"}, {"nameIdentifier": "20110603", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000020110603"}]}, {"creatorNames": [{"creatorName": "清水, 源治"}], "nameIdentifiers": [{"nameIdentifier": "53153", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-10-05"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "IN-PR-MATSUMOTO-K-116.pdf", "filesize": [{"value": "409.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 409000.0, "url": {"label": "IN-PR-MATSUMOTO-K-116.pdf", "url": "https://kanazawa-u.repo.nii.ac.jp/record/31266/files/IN-PR-MATSUMOTO-K-116.pdf"}, "version_id": "6d863fc2-fb96-41b4-ac89-60978ec695d8"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "Cadmium metal", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Cadmium oxide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Atomic Absorption", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Amalgam Separation", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "高純度金属カドミウム中の酸化カドミウムの定量", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "高純度金属カドミウム中の酸化カドミウムの定量"}, {"subitem_title": "Determoination of cadmium oxide in and on the surface of high purity cadmium metal", "subitem_title_language": "en"}]}, "item_type_id": "4", "owner": "3", "path": ["2276"], "permalink_uri": "http://hdl.handle.net/2297/24886", "pubdate": {"attribute_name": "公開日", "attribute_value": "2017-10-05"}, "publish_date": "2017-10-05", "publish_status": "0", "recid": "31266", "relation": {}, "relation_version_is_last": true, "title": ["高純度金属カドミウム中の酸化カドミウムの定量"], "weko_shared_id": -1}
高純度金属カドミウム中の酸化カドミウムの定量
http://hdl.handle.net/2297/24886
http://hdl.handle.net/2297/24886ad90f00e-6d99-461e-ae91-815f4df22a03
名前 / ファイル | ライセンス | アクション |
---|---|---|
IN-PR-MATSUMOTO-K-116.pdf (409.0 kB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2017-10-05 | |||||
タイトル | ||||||
タイトル | 高純度金属カドミウム中の酸化カドミウムの定量 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Determoination of cadmium oxide in and on the surface of high purity cadmium metal | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
木羽, 敏泰
× 木羽, 敏泰× 松本, 健× 清水, 源治 |
|||||
提供者所属 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 金沢大学イノベーション創成センター | |||||
書誌情報 |
分析化学 = Japan analyst 巻 24, 号 2, p. 116-120, 発行日 1975-02-10 |
|||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0525-1931 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00222633 | |||||
出版者 | ||||||
出版者 | The Japan Society for Analytical Chemistry = 日本分析化学会 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | l00ml分液漏斗に1M塩化アンモニウム-アンモニア水溶液(pPH10) 50ml、水銀2・5mlを入れ、窒素ガスを通じ脱酸素してから、試料の高純度金属カドミウム片を加え振り混ぜると、金属はアマルガムとなって水銀中に溶解し、酸化物はアンミン錯イオンとなって水溶液中に溶ける。水銀を分離した後、水溶液についてカドミウムの量を原子吸光法で定量すれば酸化物を求められる。本法は精度は高く、金属表面及び内部の酸化物を分別的に定量できることにも特長がある。 In a 100ml separating funnel were added 50ml of 1M ammonium chloride-aqueous ammonia buffer solution(pH1O) and 2.5ml mercury; after passing nitrogen gag sufficiently to remove oxygen from the vessel and also from the aqueous solution, several pieces of cadmium metal of high purity were put into the vessel. The content was shaken vigorously; the metal went into mercury forming cadmium-amalgam, while the cadmium oxide dissolved itself in the aqueous solution to form cadmium tetrammine complex cations. After removal of mercury from the funnel, the solution was submitted to the determination of cadmium dissolved in it by means of the atomic absorption spectrophotometry or the EDTA titration. By the above procedure a minute amount of cadmium oxide could be determined precisely with high reproducibility. The critical experiments were also done to clarify the behaviors of cadmium metal and cadmium oxide in this separation process for the purpose of establishing a suitable procedure. | |||||
権利 | ||||||
権利情報 | Copyright (c) 1975 日本分析化学会 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.jsac.or.jp/index.html | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://ci.nii.ac.jp/naid/110002907503/en/ |