International journal for reviews and communications in heterocyclic chemistry
巻
98
号
8
ページ
1044 - 1054
発行年
2019-07-17
ISSN
0385-5414
NCID
AA00663739
DOI
10.3987/COM-19-14112
出版者
Japan Institute of Heterocyclic Chemistry 日本複素環化学研究所 / Elsevier
抄録
Optically active γ-lactams were prepared by asymmetric dicarbonylation reaction of N-arylsulfonyl homoallylic amines catalyzed by palladium in the presence of copper(I) triflate. By the use of benzyl-substituted bioxazoline ligand, the corresponding γ-lactams were obtained with enantioselectivities of up to 67% ee.