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集積型二重結合を基軸とする環化反応と天然物合成
https://doi.org/10.24517/00059608
https://doi.org/10.24517/00059608d8bd1bc5-e56c-4e2c-adbe-f2b959fd4d40
名前 / ファイル | ライセンス | アクション |
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PH-PR-MUKAI-C-kaken 2015-6p.pdf (329.8 kB)
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Item type | 報告書 / Research Paper(1) | |||||
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公開日 | 2020-10-26 | |||||
タイトル | ||||||
タイトル | 集積型二重結合を基軸とする環化反応と天然物合成 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Novel reactions and total syntheses of natural products based on cumulated double bonds | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_18ws | |||||
資源タイプ | research report | |||||
ID登録 | ||||||
ID登録 | 10.24517/00059608 | |||||
ID登録タイプ | JaLC | |||||
著者 |
向, 智里
× 向, 智里 |
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著者別表示 |
Mukai, Chisato
× Mukai, Chisato |
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提供者所属 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 金沢大学医薬保健研究域薬学系 | |||||
書誌情報 |
平成26(2014)年度 科学研究費補助金 基盤研究(B) 研究成果報告書 en : 2014 Fiscal Year Final Research Report 巻 2012-04-01 – 2015-03-31, p. 6p., 発行日 2015-05-25 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | 集積型二重結合であるアレン及び関連π成分を基盤とする、新たな反応性の開拓並びに天然物の効率的合成法の確立を目的に研究を行い、以下の成果を得た。 1)アレン―アルキン体を用いたdouble Pauson-Khand型反応の開発,2)アレン―ニトロン体を用いた1,3-双極子環化付加反応の開発,3)Kopsihainanine Aの不斉全合成,4)Indicanoneの不斉全合成,5)Scytoneminの炭素アナログ合成,6)Fusicoccane型三環性骨格の効率的構築法の開発. |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The following six results based on allene chemistry were observed. 1)Regioselective intramolecular [3+2] annulation of allene-nitrones, 2)Molybdenum-mediated intramolecular double Pauson-Khand type reaction of bis(allenyne), 3)Asymmetric total synthesis of (+)-kopsihainanine A, 4)First total synthesis of (+)-indicanone, 5)The synthesis of a carbon analogue of scytonemin based on the double Pauson-Khand type adduct, 6)Syntheses of 6-8-5 tricyclic ring systems by carbonylative [2+2+1] cycloaddition of bis(allene)s. |
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内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 研究課題/領域番号:24390003, 研究期間(年度):2012-04-01 – 2015-03-31 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 出典:研究課題「集積型二重結合を基軸とする環化反応と天然物合成」課題番号24390003 (KAKEN:科学研究費助成事業データベース(国立情報学研究所)) (https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-24390003/24390003seika/)を加工して作成 |
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著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://kaken.nii.ac.jp/ja/search/?kw=70143914 | |||||
関連名称 | https://kaken.nii.ac.jp/ja/search/?kw=70143914 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-24390003/ | |||||
関連名称 | https://kaken.nii.ac.jp/ja/grant/KAKENHI-PROJECT-24390003/ | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-24390003/24390003seika/ | |||||
関連名称 | https://kaken.nii.ac.jp/ja/report/KAKENHI-PROJECT-24390003/24390003seika/ |