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Visualizing Nanoscale Distribution of Corrosion Cells by Open-Loop Electric Potential Microscopy
https://doi.org/10.24517/00009469
https://doi.org/10.24517/00009469694a1c0b-9945-4d2c-94d6-307f6209400e
名前 / ファイル | ライセンス | アクション |
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TE-PR-FUKUMA-T-2575.pdf (1.7 MB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-10-03 | |||||
タイトル | ||||||
タイトル | Visualizing Nanoscale Distribution of Corrosion Cells by Open-Loop Electric Potential Microscopy | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
ID登録 | ||||||
ID登録 | 10.24517/00009469 | |||||
ID登録タイプ | JaLC | |||||
著者 |
Honbo, Kyoko
× Honbo, Kyoko× Ogata, Shoichiro× Kitagawa, Takuya× Okamoto, Takahiro× Kobayashi, Naritaka× Sugimoto, Itto× Shima, Shohei× Fukunaga, Akira× Takatoh, Chikako× Fukuma, Takeshi |
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著者別表示 |
福間, 剛士
× 福間, 剛士 |
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提供者所属 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 金沢大学ナノ生命科学研究所 | |||||
書誌情報 |
ACS Nano 巻 10, 号 2, p. 2575-2583, 発行日 2016-02-23 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 1936-0851 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1021/acsnano.5b07552 | |||||
出版者 | ||||||
出版者 | American Chemical Society | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Corrosion is a traditional problem but still one of the most serious problems in industry. To reduce the huge economic loss caused by corrosion, tremendous effort has been made to understand, predict and prevent it. Corrosion phenomena are generally explained by the formation of corrosion cells at a metal-electrolyte interface. However, experimental verification of their nanoscale distribution has been a major challenge owing to the lack of a method able to visualize the local potential distribution in an electrolytic solution. In this study, we have investigated the nanoscale corrosion behavior of Cu fine wires and a duplex stainless steel by in situ imaging of local corrosion cells by open-loop electric potential microscopy (OL-EPM). For both materials, potential images obtained by OL-EPM show nanoscale contrasts, where areas of higher and lower potential correspond to anodic areas (i.e., corrosion sites) and cathodic areas, respectively. This imaging capability allows us to investigate the real-time transition of local corrosion sites even when surface structures show little change. This is particularly useful for investigating reactions under surface oxide layers or highly corrosion-resistant materials as demonstrated here. The proposed technique should be applicable to the study of other redox reactions on a battery electrode or a catalytic material. The results presented here open up such future applications of OL-EPM in nanoscale electrochemistry. © 2016 American Chemical Society. | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Embargo Period 12 months | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |