WEKO3
インデックスリンク
アイテム
{"_buckets": {"deposit": "9783d399-bd43-463e-b803-c4d66a023994"}, "_deposit": {"created_by": 3, "id": "10577", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "10577"}, "status": "published"}, "_oai": {"id": "oai:kanazawa-u.repo.nii.ac.jp:00010577", "sets": ["937"]}, "author_link": ["16085", "306", "16083", "16084", "60"], "item_4_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2014-03-14", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "10", "bibliographicPageStart": "101101", "bibliographicVolumeNumber": "140", "bibliographic_titles": [{"bibliographic_title": "Journal of Chemical Physics"}]}]}, "item_4_description_21": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Total-reflection X-ray absorption fine structure (TR-XAFS) technique was applied for the first time to an interface between two immiscible electrolyte solutions under potentiostatic control. The hydration structure of bromide ions was investigated at polarized 2-octanone/water interfaces. TR-XAFS spectra at Br K-edge measured in the presence of hexyltrimethylammonium bromide (C 6TAB) were slightly modified depending on the Galvani potential difference (Δowφ). The extended X-ray absorption fine structure analysis exposed hydration structure changes of bromide ions at the polarized interface. The coordination structure of bromide ions at the interface could be analyzed as compared with bromide ions dissolved in aqueous solution and Br --exchanged resin having quaternary ammonium groups. The results indicated that bromide ions were associated with C6TA+ at the polarized interface. The relative contribution of ion association form of bromide ions with quaternary ammonium groups was enhanced at a potential close to the ion transfer of C6TA+, where the interfacial concentration of C6TA+ is increased as a function of Δowφ. © 2014 AIP Publishing LLC.", "subitem_description_type": "Abstract"}]}, "item_4_publisher_17": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "American Institute of Physics (AIP)"}]}, "item_4_relation_12": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1063/1.4867899", "subitem_relation_type_select": "DOI"}}]}, "item_4_source_id_11": {"attribute_name": "NCID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00694991", "subitem_source_identifier_type": "NCID"}]}, "item_4_source_id_9": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0021-9606", "subitem_source_identifier_type": "ISSN"}]}, "item_4_version_type_25": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Nagatani, Hirohisa"}], "nameIdentifiers": [{"nameIdentifier": "306", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "60237427", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=60237427"}, {"nameIdentifier": "90346297", "nameIdentifierScheme": "金沢大学研究者情報", "nameIdentifierURI": "http://ridb.kanazawa-u.ac.jp/public/detail.php?kaken=90346297"}, {"nameIdentifier": "90346297", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000090346297"}]}, {"creatorNames": [{"creatorName": "Harada, Makoto"}], "nameIdentifiers": [{"nameIdentifier": "16083", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tanida, Hajime"}], "nameIdentifiers": [{"nameIdentifier": "16084", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Sakae, Hiroki"}], "nameIdentifiers": [{"nameIdentifier": "16085", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Imura, Hisanori"}], "nameIdentifiers": [{"nameIdentifier": "60", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "60142923", "nameIdentifierScheme": "金沢大学研究者情報", "nameIdentifierURI": "http://ridb.kanazawa-u.ac.jp/public/detail.php?kaken=60142923"}, {"nameIdentifier": "60142923", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000060142923"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-10-03"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "SC-PR-NAGATANI-H-101101.pdf", "filesize": [{"value": "562.7 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 562700.0, "url": {"label": "SC-PR-NAGATANI-H-101101.pdf", "url": "https://kanazawa-u.repo.nii.ac.jp/record/10577/files/SC-PR-NAGATANI-H-101101.pdf"}, "version_id": "234e213b-48c8-49d1-9971-927b46a3c873"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Communication: Coordination structure of bromide ions associated with hexyltrimethylammonium cations at liquid/liquid interfaces under potentiostatic control as studied by total-reflection X-ray absorption fine structure", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Communication: Coordination structure of bromide ions associated with hexyltrimethylammonium cations at liquid/liquid interfaces under potentiostatic control as studied by total-reflection X-ray absorption fine structure"}]}, "item_type_id": "4", "owner": "3", "path": ["937"], "permalink_uri": "http://hdl.handle.net/2297/37537", "pubdate": {"attribute_name": "公開日", "attribute_value": "2017-10-03"}, "publish_date": "2017-10-03", "publish_status": "0", "recid": "10577", "relation": {}, "relation_version_is_last": true, "title": ["Communication: Coordination structure of bromide ions associated with hexyltrimethylammonium cations at liquid/liquid interfaces under potentiostatic control as studied by total-reflection X-ray absorption fine structure"], "weko_shared_id": -1}
Communication: Coordination structure of bromide ions associated with hexyltrimethylammonium cations at liquid/liquid interfaces under potentiostatic control as studied by total-reflection X-ray absorption fine structure
http://hdl.handle.net/2297/37537
http://hdl.handle.net/2297/3753750494de5-891a-46f3-8a27-8a402f7150b9
名前 / ファイル | ライセンス | アクション |
---|---|---|
SC-PR-NAGATANI-H-101101.pdf (562.7 kB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2017-10-03 | |||||
タイトル | ||||||
タイトル | Communication: Coordination structure of bromide ions associated with hexyltrimethylammonium cations at liquid/liquid interfaces under potentiostatic control as studied by total-reflection X-ray absorption fine structure | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Nagatani, Hirohisa
× Nagatani, Hirohisa× Harada, Makoto× Tanida, Hajime× Sakae, Hiroki× Imura, Hisanori |
|||||
書誌情報 |
Journal of Chemical Physics 巻 140, 号 10, p. 101101, 発行日 2014-03-14 |
|||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0021-9606 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00694991 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1063/1.4867899 | |||||
出版者 | ||||||
出版者 | American Institute of Physics (AIP) | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Total-reflection X-ray absorption fine structure (TR-XAFS) technique was applied for the first time to an interface between two immiscible electrolyte solutions under potentiostatic control. The hydration structure of bromide ions was investigated at polarized 2-octanone/water interfaces. TR-XAFS spectra at Br K-edge measured in the presence of hexyltrimethylammonium bromide (C 6TAB) were slightly modified depending on the Galvani potential difference (Δowφ). The extended X-ray absorption fine structure analysis exposed hydration structure changes of bromide ions at the polarized interface. The coordination structure of bromide ions at the interface could be analyzed as compared with bromide ions dissolved in aqueous solution and Br --exchanged resin having quaternary ammonium groups. The results indicated that bromide ions were associated with C6TA+ at the polarized interface. The relative contribution of ion association form of bromide ions with quaternary ammonium groups was enhanced at a potential close to the ion transfer of C6TA+, where the interfacial concentration of C6TA+ is increased as a function of Δowφ. © 2014 AIP Publishing LLC. | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |