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Highly Selective Synergism for the Extraction of Lanthanoid(III) Ions with β-Diketones and Trioctylphosphine Oxide in an Ionic Liquid
http://hdl.handle.net/2297/36910
http://hdl.handle.net/2297/3691055a934cf-015e-45d9-ad95-948e5207a08d
名前 / ファイル | ライセンス | アクション |
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SC-PR-MORITA-K-323.pdf (485.0 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-10-03 | |||||
タイトル | ||||||
タイトル | Highly Selective Synergism for the Extraction of Lanthanoid(III) Ions with β-Diketones and Trioctylphosphine Oxide in an Ionic Liquid | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Okamura, Hiroyuki
× Okamura, Hiroyuki× Takagi, Hitomi× Isomura, Taku× Morita, Kotaro× Nagatani, Hirohisa× Imura, Hisanori |
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書誌情報 |
分析化学 = Analytical Sciences 巻 30, 号 3, p. 323-325, 発行日 2014-01-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0525-1931 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00222633 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.2116/analsci.30.323 | |||||
出版者 | ||||||
出版者 | 日本分析化学会 = The Japan Society for Analytical Chemistry | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Selective synergism for the extraction of lanthanoids(III) (Ln) with β-diketones such as 2-thenoyltrifluoroacetone, 2-naphthoyltrifluoroacetone, and benzoylacetone has been investigated in the presence of trioctylphosphine oxide as a hydrophobic neutral ligand in 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide as an ionic liquid. The extractability of heavier Ln was remarkably enhanced, resulting in a significant improvement in the separation of Ln. It was found that the present synergism is ascribed to the formation of cationic ternary complexes, followed by ion exchange into the ionic liquid. | |||||
権利 | ||||||
権利情報 | Copyright © The Japan Society for Analytical Chemistry 2014 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.jsac.jp/ | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://www.jstage.jst.go.jp/browse/bunsekikagaku |