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Dinuclear Cobalt(II) Complexes Containing 1,3-(or 1,5-)Bis[bis(2-pyridylmethyl)amino]-2-propanolato (or -3-pentanolato): Preparation and Reaction with Molecular Oxygen
http://hdl.handle.net/2297/38282
http://hdl.handle.net/2297/38282b9370092-404c-4d89-bee6-84ca28fe0a20
名前 / ファイル | ライセンス | アクション |
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SC-PR-SUZUKI-M-1115.pdf (984.2 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-10-03 | |||||
タイトル | ||||||
タイトル | Dinuclear Cobalt(II) Complexes Containing 1,3-(or 1,5-)Bis[bis(2-pyridylmethyl)amino]-2-propanolato (or -3-pentanolato): Preparation and Reaction with Molecular Oxygen | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Suzuki, Masatatsu
× Suzuki, Masatatsu× Sugisawa, Toshiharu× Uehara, Akira |
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著者別表示 |
鈴木, 正樹
× 鈴木, 正樹× 上原, 章 |
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書誌情報 |
Bulletin of the Chemical Society of Japan 巻 63, 号 4, p. 1115-1120, 発行日 1990-01-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0009-2673 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00580132 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1246/bcsj.63.1115 | |||||
出版者 | ||||||
出版者 | The Chemical Society of Japan = 日本化学会 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Two dinuclear cobalt(II,II) complexes, [Co2(tpdp)(CH3COO)](ClO4)2·0.5H2O (1) and [Co2(tmdp)(CH3COO)](ClO4)2·H2O (2), were prepared, where Htpdp and Htmdp are 1,3-bis[bis(2-pyridylmethyl)amino]-2-propanol and 1,5-bis[bis(2-pyridylmethyl)amino]-3-pentanol respectively. Their electronic spectral and magnetic data revealed that 1 and 2 are five-coordinate in the high-spin state, in the same manner as [Co2(bpmp)(CH3COO)]2+ (3) (Hbpmp=2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-methylphenol). The complexes reacted with molecular oxygen to form μ-peroxo complexes in dichloromethane and acetonitrile. The oxygen affinity of the complexes decreased in the order of 3>2>1. The relationships between the oxygen affinities and (1) the donor abilities of dinucleating ligands, (2) the energies of the charge-transfer bands (O22− to Co3+) of the μ-peroxo complexes, and (3) the redox potentials of the Co3+–O2−–Co3+/Co3+–O22−–Co3+ couple indicated that a steric effect arising from the dinucleating ligands contributes significantly to the oxygen affinities of the complexes. | |||||
権利 | ||||||
権利情報 | Copyright © The Chemical Society of Japan 日本化学会 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://www.jstage.jst.go.jp/browse/bcsj | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.chemistry.or.jp/ |