WEKO3
インデックスリンク
アイテム
{"_buckets": {"deposit": "3de7d9a1-306d-4780-88bd-4d520d900c4a"}, "_deposit": {"created_by": 3, "id": "14923", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "14923"}, "status": "published"}, "_oai": {"id": "oai:kanazawa-u.repo.nii.ac.jp:00014923", "sets": ["1135"]}, "author_link": ["24593", "26419", "26779"], "item_4_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2002-07-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "7", "bibliographicPageEnd": "1234", "bibliographicPageStart": "1231", "bibliographicVolumeNumber": "57", "bibliographic_titles": [{"bibliographic_title": "Heterocycles"}]}]}, "item_4_description_21": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "Nucleophiles react with 1-methoxy-3-(2-nitrovinyl)indole (3) at the 2-position regioselectively in a dipolar aprotic solvent (DMF or HMPA), while in THF they undergo Michael addition to the β-carbon of nitrovinyl side chain. Depending on bases employed, the resultant Michael addition products (6d, 10, and 11) are found to undergo interesting cyclizations to give novel 3-substituted 1-methoxyindoles (7, 9, and 12).", "subitem_description_type": "Abstract"}]}, "item_4_description_5": {"attribute_name": "提供者所属", "attribute_value_mlt": [{"subitem_description": "金沢大学大学院自然科学研究科生理活性物質科学", "subitem_description_type": "Other"}]}, "item_4_publisher_17": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "日本複素環化学研究所"}]}, "item_4_rights_23": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "日本複素環化学研究所の許諾を得て登録"}]}, "item_4_source_id_11": {"attribute_name": "NCID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00663739", "subitem_source_identifier_type": "NCID"}]}, "item_4_version_type_25": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "metadata only access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_14cb"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yamada, Koji"}], "nameIdentifiers": [{"nameIdentifier": "26779", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "80272962", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=80272962"}, {"nameIdentifier": "80272962", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000080272962"}]}, {"creatorNames": [{"creatorName": "Yamada, Fumio"}], "nameIdentifiers": [{"nameIdentifier": "26419", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "80135087", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=80135087"}, {"nameIdentifier": "80135087", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000080135087"}]}, {"creatorNames": [{"creatorName": "Somei, Masanori"}], "nameIdentifiers": [{"nameIdentifier": "24593", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "20110546", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000020110546"}]}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "1 methoxy 3 (2 nitrovinyl)indole", "subitem_subject_scheme": "Other"}, {"subitem_subject": "indole derivative", "subitem_subject_scheme": "Other"}, {"subitem_subject": "solvent", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Reactions of 1-methoxy-3-(2-nitrovinyl)indole with nucleophiles: An interesting solvent effect and a novel preparation of 3-substituted 1-methoxyindoles", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Reactions of 1-methoxy-3-(2-nitrovinyl)indole with nucleophiles: An interesting solvent effect and a novel preparation of 3-substituted 1-methoxyindoles"}]}, "item_type_id": "4", "owner": "3", "path": ["1135"], "permalink_uri": "http://hdl.handle.net/2297/4371", "pubdate": {"attribute_name": "公開日", "attribute_value": "2017-10-03"}, "publish_date": "2017-10-03", "publish_status": "0", "recid": "14923", "relation": {}, "relation_version_is_last": true, "title": ["Reactions of 1-methoxy-3-(2-nitrovinyl)indole with nucleophiles: An interesting solvent effect and a novel preparation of 3-substituted 1-methoxyindoles"], "weko_shared_id": -1}
Reactions of 1-methoxy-3-(2-nitrovinyl)indole with nucleophiles: An interesting solvent effect and a novel preparation of 3-substituted 1-methoxyindoles
http://hdl.handle.net/2297/4371
http://hdl.handle.net/2297/43715dcb8591-6100-41d9-b21e-9874a37c7b3d
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2017-10-03 | |||||
タイトル | ||||||
タイトル | Reactions of 1-methoxy-3-(2-nitrovinyl)indole with nucleophiles: An interesting solvent effect and a novel preparation of 3-substituted 1-methoxyindoles | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
Yamada, Koji
× Yamada, Koji× Yamada, Fumio× Somei, Masanori |
|||||
提供者所属 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 金沢大学大学院自然科学研究科生理活性物質科学 | |||||
書誌情報 |
Heterocycles 巻 57, 号 7, p. 1231-1234, 発行日 2002-07-01 |
|||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00663739 | |||||
出版者 | ||||||
出版者 | 日本複素環化学研究所 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Nucleophiles react with 1-methoxy-3-(2-nitrovinyl)indole (3) at the 2-position regioselectively in a dipolar aprotic solvent (DMF or HMPA), while in THF they undergo Michael addition to the β-carbon of nitrovinyl side chain. Depending on bases employed, the resultant Michael addition products (6d, 10, and 11) are found to undergo interesting cyclizations to give novel 3-substituted 1-methoxyindoles (7, 9, and 12). | |||||
権利 | ||||||
権利情報 | 日本複素環化学研究所の許諾を得て登録 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |