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歪みを内包する化合物を用いる光活性化型反応の開発
https://doi.org/10.24517/00058370
https://doi.org/10.24517/00058370134c5310-6f29-409f-a3b4-61025661c8cc
名前 / ファイル | ライセンス | アクション |
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FR-PR-MISHIRO-K-kaken 2020-7p.pdf (839.8 kB)
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Item type | 報告書 / Research Paper(1) | |||||
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公開日 | 2021-04-30 | |||||
タイトル | ||||||
タイトル | 歪みを内包する化合物を用いる光活性化型反応の開発 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Development of phototriggered reactions using strained molecules | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_18ws | |||||
資源タイプ | research report | |||||
ID登録 | ||||||
ID登録 | 10.24517/00058370 | |||||
ID登録タイプ | JaLC | |||||
著者 |
三代, 憲司
× 三代, 憲司 |
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著者別表示 |
Mishiro, Kenji
× Mishiro, Kenji |
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提供者所属 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 金沢大学新学術創成研究機構 | |||||
書誌情報 |
令和1(2019)年度 科学研究費補助金 若手研究 研究成果報告書 en : 2019 Fiscal Year Final Research Report 巻 2018-04-01 – 2020-03-31, p. 7p., 発行日 2020-05-25 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | 生体分子や機能性材料の化学修飾に有用な新規光反応開発に取り組んだ。 アミノシクロプロペノンとカルボン酸共存下光照射を行うことでカルボン酸にアミノシクロプロペノン由来の官能基が導入されたケトンを迅速に形成する反応の開発に成功した。本成果はJ. Org. Chem. 2018, 83, 13595にて論文発表を行った。また、穏和な条件でシクロプロペノンから高反応性のアルキンを生成するため、可視光応答性触媒を利用する新反応開発に成功した。本反応により従来適用できなかった不安定な基質共存下の反応が可能になった。本成果はOrg. Lett. 2019, 21, 4101にて論文発表を行った。 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | We developed two kind of novel photochemical reactions that would be potentially useful for functionalization of biomolecules and polymer materials. First, we developed a phototriggered ketone formation reaction from an aminocyclopropenone and a carboxylic acid. The reaction efficiently proceeds under intense light irradiation. By the reaction, functional groups on the aminocyclopropenone are covalently connected with the carboxylic acid. The result was published in J. Org. Chem. 2018, 83, 13595. Second, we developed a phototriggered active alkyne generation reactions using visible light responsive photocatalysts. The reaction condition was effective to generate highly reactive ynamine and cyclooctyne, and the generated alkynes can be used for the chemical reactions without isolation. The conditions were compatible with a UV sensitive substrate which cannot tolerate a classical direct UV irradiation conditions. The result was published in Org. Lett. 2019, 21, 4101. | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 研究課題/領域番号:18K14864, 研究期間(年度):2018-04-01 – 2020-03-31 | |||||
内容記述 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 出典:「歪みを内包する化合物を用いる光活性化型反応の開発」研究成果報告書 課題番号18K14864 (KAKEN:科学研究費助成事業データベース(国立情報学研究所)) (https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-18K14864/18K14864seika/)を加工して作成 |
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著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://kaken.nii.ac.jp/search/?qm=60776079 | |||||
関連名称 | https://kaken.nii.ac.jp/search/?qm=60776079 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18K14864/ | |||||
関連名称 | https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-18K14864/ | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-18K14864/18K14864seika/ | |||||
関連名称 | https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-18K14864/18K14864seika/ |