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Thermal Reactions of the Nickel(II) Complexes Containing 1-Phenyl-1,2-ethanediamine in the Solid Phase
http://hdl.handle.net/2297/37509
http://hdl.handle.net/2297/37509f274568a-b6b0-4b28-8ad0-a985edbaa37a
名前 / ファイル | ライセンス | アクション |
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LE-PR-IHARA-Y-3248-3251.pdf (291.7 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-10-02 | |||||
タイトル | ||||||
タイトル | Thermal Reactions of the Nickel(II) Complexes Containing 1-Phenyl-1,2-ethanediamine in the Solid Phase | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Ihara, Yoshinori
× Ihara, Yoshinori |
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書誌情報 |
Bulletin of the Chemical Society of Japan 巻 58, 号 11, p. 3248-3251, 発行日 1985-01-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0009-2673 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA12026255 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1246/bcsj.58.3248 | |||||
出版者 | ||||||
出版者 | 日本化学会=The Chemical Society of Japan | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Nickel(II) complexes [Ni(phenen)2](ClO4)2 and [Ni(H2O)2(phenen)2]X2 (phenen=1-phenyl-1,2-ethanediamine, X=Cl, Br, or NO3) were prepared, and their thermal behavior was investigated in the solid phase. The nitrate showed a thermochromism consisting of two steps, violet→yellow→violet, which corresponds to a structural change from an octahedral diaqua complex to a square planar anhydride, and then to the octahedral dinitrato complex, respectively. Both the chloride and bromide were converted into the octahedral dianiono complexes by thermal deaquation-anation, retaining their octahedral configuration. However, no change was observed in the perchlorate, which is invariably square planar. | |||||
権利 | ||||||
権利情報 | Copyright © 日本化学会 The Chemical Society of Japan|許可を得て登録 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.chemistry.or.jp/ | |||||
関連URI | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://www.jstage.jst.go.jp/article/bcsj1926/58/11/58_11_3248/_article |