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Characterization of ZnS-layer-inserted bulk-heterojunction organic solar cells by ac impedance spectroscopy
https://doi.org/10.24517/00009721
https://doi.org/10.24517/000097211165cd6d-781a-49da-a408-c6a3f4cef414
名前 / ファイル | ライセンス | アクション |
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TE-PR-KUWABARA-T-124513.pdf (557.8 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2017-10-03 | |||||
タイトル | ||||||
タイトル | Characterization of ZnS-layer-inserted bulk-heterojunction organic solar cells by ac impedance spectroscopy | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
ID登録 | ||||||
ID登録 | 10.24517/00009721 | |||||
ID登録タイプ | JaLC | |||||
著者 |
Kuwabara, Takayuki
× Kuwabara, Takayuki× Nakamoto, Masayuki× Kawahara, Yoshitaka× Yamaguchi, Takahiro× Takahashi, Kohshin |
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著者別表示 |
桑原, 貴之
× 桑原, 貴之× 山口, 孝浩× 高橋, 光信 |
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提供者所属 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 金沢大学理工研究域物質化学系 | |||||
書誌情報 |
Journal of Applied Physics 巻 105, 号 12, p. 124513, 発行日 2009-01-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0021-8979 | |||||
NCID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00693547 | |||||
DOI | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1063/1.3153970 | |||||
出版者 | ||||||
出版者 | American Institute of Physics | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A fluorine-doped tin oxide (FTO)/zinc sulfide (ZnS)/[6,6]-phenyl C 61 butyric acid methyl ester (PCBM): regioregular poly(3-hexylthiophene) P3HT)/poly(3,4-ethylenedioxylenethiophene): poly(4-styrene sulfonic acid) (PEDOT:PSS)/Au type organic solar cell (FTO/ZnS/PCBM:P3HT/PEDOT:PSS/Au, ZnS cell) with a 1 cm2 active area was first developed using transparent ZnS prepared on a FTO electrode by a chemical bath deposition method. The ZnS inserted solar cells were investigated by photocurrent-voltage (I-V) and ac impedance spectroscopy (IS) measurements. In photo I-V measurements, the ZnS cell exhibited scattered power conversion efficiencies (η) of 0.7%-1.2% when the FTO/ZnS electrode was not immersed in various aqueous solutions before the fabrication of the ZnS cells. In contrast, the solar cells with a surface-modified FTO/ZnS electrode by immersing in 0.1M Na2 S solutions at pH 7-9 containing hydrosulfide ions (HS-) exhibited reproducible η of 1.5%-1.7%. The electric resistance components in the cell consisting of five layers were separately estimated by the IS measurement. The larger of the solar cell using HS- modified ZnS was explained by the fact that the charge transport resistance at the ZnS/PCBM:P3HT interface became smaller due to this surface modification. When a continuous light irradiation was carried out for the modified cells, the resistance at the ZnS/PCBM:P3HT interface increased, being accompanied by the decrease in the η. That is, the cell performance was controlled mainly by charge transport velocity at the ZnS/PCBM:P3HT interface. © 2009 American Institute of Physics. | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |