複数の異なる金属原子を含む錯体や,中間体を経由する有機合成反応の開発に挑む.一般的に,有機合成化学は精密化に集中するあまり,複雑な分子制御に弱点を抱えている.その制御法の先駆的例として,本研究は,独自の分子設計に基づく「複雑な反応中間体発生と制御」に取り組み,従来法では不可能であった様々な反応開発に成功した.
The present study describes the generation of synergistic intermediates derived from multinuclear complexes in organic reactions. Typically, organic chemistry focuses on the development of simple reactive intermediates due to the disadvantageous using complicated molecules. The original strategies for the construction of “complicated reactive intermediates in situ” were achieved during our course of study. The synergistic effects realized the unprecedented control of organic reactions, which could not be achieved with the conventional systems.
異核金属クラスター触媒による複数活性中心の制御法開拓
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SC-PR-ENDO-K-kaken 2013-5p.pdf
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