2026-03-12T14:09:13Z https://kanazawa-u.repo.nii.ac.jp/oai

oai:kanazawa-u.repo.nii.ac.jp:00010792 2024-06-25T05:46:01Z 4162:4169:4188

Synthesis of meta-methoxyphenyl substituted tetraazaporphyrin and corrolazine phosphorus(V) complexes 古山, 渓行 Furuyama, Taniyuki 16527 30584528 30584528 Sugiya, Yusuke 16528 Yoshida, Takuya 16529 Kobayashi, Nagao 16530 Octa-(meta-methoxyphenyl) substituted tetraazaporphyrin (TAP, 1) and corrolazine (Cor, 4) phosphorus(V) complexes have been synthesized and characterized. 1 has a blue-shifted, small charge transfer (CT) band while para-methoxyphenyl substituted PTAP 2 has a red-shifted, intense CT band. The difference could be interpreted as an inductive effect of the meta-methoxy groups. The position and intensity of the absorption bands of 1 are well matched to the trend of para-substituted PTAPs. The synthesis of PCor from free-base TAP was also investigated. The PCor was not generated directly but from a PTAP intermediate. © 2016 World Scientific Publishing Company. Embargo Period 12 months 金沢大学ナノマテリアル研究所 journal article World Scientific Publishing Co. Pte Ltd 2016-08-01 AM application/pdf Journal of Porphyrins and Phthalocyanines 8-11 20 1075 1081 AA11202421 1088-4246 https://kanazawa-u.repo.nii.ac.jp/record/10792/files/SC-PR-FURUYAMA-T-1075.pdf https://doi.org/10.24517/00010779 http://hdl.handle.net/2297/46749 https://kanazawa-u.repo.nii.ac.jp/records/10792 eng 10.1142/S1088424616500619