{"created":"2023-07-27T06:26:30.459099+00:00","id":10250,"links":{},"metadata":{"_buckets":{"deposit":"b560b81d-d3f0-4181-a354-d5dc1655c1de"},"_deposit":{"created_by":3,"id":"10250","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"10250"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00010250","sets":["4162:4169:4188"]},"author_link":["15140","15339","15335","15338","15337","95392","15334","15336"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2001-07-15","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"045211-7","bibliographicPageStart":"045211-1","bibliographicVolumeNumber":"64","bibliographic_titles":[{"bibliographic_title":"Physical Review B"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"遠藤, 一央"}],"nameIdentifiers":[{},{}]}]},"item_4_description_16":{"attribute_name":"その他の識別子","attribute_value_mlt":[{"subitem_description":"AA11187113","subitem_description_type":"Other"}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The results of x-ray fluorescence measurements of thiophenes @regioregular poly ~3-hexylthiophene ~P3HT! and a,v-dihexylquaterthiophene ~DHa4T!# and phtalocyanines @copper phtalocyanine ~CuPc! and copper hexadecafluorophtalocyanine (F16CuPc)# are presented. Experimental carbon, nitrogen, fluorine Ka and sulphur, copper L2,3 x-ray emission spectra are compared with ultraviolet photoemission spectroscopy spectra and deMon density-functional theory calculations of model molecules. We find that the carbon Ka emission is almost identical for P3HT and DHa4T. This indicates that the electronic structure of the p system is not affected by the presence of the side group. The ratio of emission intensities of the Cu L2 to Cu L3 intensities is found to be smaller by a factor of 2 for CuPc and F16CuPc than it is for pure metal. This demonstrates the strong covalency in phalocyanines.","subitem_description_type":"Abstract"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学ナノマテリアル研究所 / 金沢大学理工研究域数物科学系 / 金沢大学大学院自然科学研究科物質情報解析","subitem_description_type":"Other"}]},"item_4_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00010237","subitem_identifier_reg_type":"JaLC"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The American Physical Society"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1103/physrevb.64.045211","subitem_relation_type_select":"DOI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2000 The American Physical Society"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"10980121","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kurmaev, E.Z."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shamin, S.N."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Galakhov, V.R."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Moewes, A."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Otsuka, T."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Koizume, S."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Endo, Kazunaka"}],"nameIdentifiers":[{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"SC-PR-ENDO-K-e045211.pdf","filesize":[{"value":"123.4 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-ENDO-K-e045211.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/10250/files/SC-PR-ENDO-K-e045211.pdf"},"version_id":"7361a16d-f18c-41d3-9c8d-1a4601e0f512"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Electronic structure of thiophenes and phthalocyanines","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Electronic structure of thiophenes and phthalocyanines"}]},"item_type_id":"4","owner":"3","path":["4188"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"10250","relation_version_is_last":true,"title":["Electronic structure of thiophenes and phthalocyanines"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T09:50:54.613574+00:00"}