{"created":"2023-07-27T06:26:35.021361+00:00","id":10360,"links":{},"metadata":{"_buckets":{"deposit":"8f235594-5e59-448e-8583-ea1ec1892e07"},"_deposit":{"created_by":3,"id":"10360","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"10360"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00010360","sets":["934:935:937"]},"author_link":["15633","15631","15630","15632","15629"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-11-02","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"34","bibliographicPageEnd":"5163","bibliographicPageStart":"5156","bibliographic_titles":[{"bibliographic_title":"European Journal of Inorganic Chemistry"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Oxidation, reactions of the reduced decavanadate [VIV2Vv8O26]4- (1) with halide guest anions were investigated for the synthesis of Vv host molecules. The reaction with Cl- afforded a new dodecavanadate, [HVV12O32(C1)]4-(3), which incorporated the guest chloride anion. The polyoxovanadate framework of 3 is different from, the bowl-shaped dodecavanadate [VV12O 32(CH3CN)]4- (2). The structure of 3 is regarded as a trilacunary counterpart of the pentadecavanadate [V V9VIV8O36C1] 4-. Employment: of an F-template yielded the layered polyoxovanadate [HVV11O29F2] 4- (4). The framework of 4 is a monolacunary structure of the fluoride-incorporated dodecavanadate [H6VV2VIv10O30F2] 6-, in which one of the VO groups at the belt position is removed. The three vana-dium atoms in the capping units are connected, by (μ3-F bridges. Reaction with Br provided [HVv12O32(Br)]4- (5) with minor formation of [H3VV10O28]3- Interconversion reactions between 2, 3, and 4 proceeded as follows: the reaction of 2 with Cl- prompted, an isomerization reaction of the bowl-type framework, affording 3; the reaction of 3 with F- gave 4; the reaction of 4 with CH3CN reproduced acetonitrile-incorporated 2. Complexes 3 and 4 were characterized by X-ray analysis. Polyoxovanadates 3 and 4, with the highest oxidation cores, exhibited distinct signals in the 51V NMR spectra, corresponding to lacunary polyoxovanadate geometries. © Wiley-VCH Verlag GmbH & Co. KGaA.","subitem_description_type":"Abstract"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley-Blackwell"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/ejic.200900605","subitem_relation_type_select":"DOI"}}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA11181707","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1434-1948","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Okaya, Kenji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kobayashi, Tetsuhiro"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Koyama, Yuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hayashi, Yoshihito"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Isobe, Kiyoshi"}],"nameIdentifiers":[{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"SC-PR-HAYASHI-Y-5156.pdf","filesize":[{"value":"656.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"SC-PR-HAYASHI-Y-5156.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/10360/files/SC-PR-HAYASHI-Y-5156.pdf"},"version_id":"37bcbc44-7fe2-45c8-8799-90c4a1beafca"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Formation of vv lacunary polyoxovanadates and interconversion reactions of dodecavanadate species","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Formation of vv lacunary polyoxovanadates and interconversion reactions of dodecavanadate species"}]},"item_type_id":"4","owner":"3","path":["937"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"10360","relation_version_is_last":true,"title":["Formation of vv lacunary polyoxovanadates and interconversion reactions of dodecavanadate species"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-28T01:41:48.908713+00:00"}