{"created":"2023-07-27T06:26:37.232050+00:00","id":10414,"links":{},"metadata":{"_buckets":{"deposit":"1f36e8e1-ca41-4480-8b1c-23a02c474460"},"_deposit":{"created_by":3,"id":"10414","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"10414"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00010414","sets":["4162:4169:4188"]},"author_link":["15140","15770","15768","15765","110381","15767","15769","15766"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2002-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"476","bibliographicPageStart":"471","bibliographicVolumeNumber":"9","bibliographic_titles":[{"bibliographic_title":"Journal of Surface Analysis"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"遠藤, 一央"}],"nameIdentifiers":[{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We examined surface damage for polyvinyl chloride (PVC) sample after 260 minutes at an unmonochromated Al Kα X-ray source power at 600 W, because PVC decomposes very quickly due to the X-ray irradiation. The pendant Cl groups of the PVC were estimated to cleave more rapidly than C-C bonds in the main chains from two-center bond energies calculated by AM1 method using the model pentamer. The valence XPS of the polymer at the initial time, and after 120 and 260 minutes of X-ray irradiation were analyzed by deMon density-functional theory (DFT) calculations using the model pentamer. The simulated results afforded us that the pendant Cl groups of PVC cleave mainly due to the X-ray radiation.","subitem_description_type":"Abstract"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学ナノマテリアル研究所 / 金沢大学理工研究域数物科学系 / 金沢大学大学院自然科学研究科物質情報解析","subitem_description_type":"Other"}]},"item_4_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00010401","subitem_identifier_reg_type":"JaLC"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"表面分析研究会 = Surface Analysis Society of Japan"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1384/jsa.9.471","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.sasj.jp/jpn-index.html","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://japanlinkcenter.org/JST.JSTAGE/jsa/9.471","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright (c) 2003 一般社団法人　表面分析研究会"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA12022731","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1347-8400","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Takaoka, K."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Koizumi, S."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Maeda, S."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Bureau, C."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Endo, Kazunaka"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Hyodo, K."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Miura, H."}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"SC-PR-ENO-K-9_471[1].pdf","filesize":[{"value":"407.2 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-ENO-K-9_471[1].pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/10414/files/SC-PR-ENO-K-9_471[1].pdf"},"version_id":"75c5c80c-cb5e-45ea-9299-2000b01c8448"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Surface Damage of PVC Polymers during XPS Analysis","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Surface Damage of PVC Polymers during XPS Analysis"}]},"item_type_id":"4","owner":"3","path":["4188"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"10414","relation_version_is_last":true,"title":["Surface Damage of PVC Polymers during XPS Analysis"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T09:50:57.269359+00:00"}