@article{oai:kanazawa-u.repo.nii.ac.jp:00010580, author = {Ogawa, Susumu and Hirayama, Naoki and Honjo, Takaharu and Chayama, Kenji}, journal = {Solvent Extraction Research and Development, Japan}, month = {Jan}, note = {The extractability of Ag(I) with TTA in benzene was enhanced in the presence of HTCO. The extraction equilibrium was reached within 5 min. It was found that Ag(I) is extracted as the ion-pair complex, Ag(I) (HTCO) TTA. From the slope analysis, it was estimated that the Ag(I) species was oxidized to Ag(II) as an ion-pair complex, Ag(II) (HTCO) (TTA)2. The presence of π electrons or chlorine atoms in diluent molecules such as benzene, toluene, monochlorobenzene, and chloroform, may affect the oxidation of Ag(I) during the extraction.}, pages = {77--83}, title = {Extraction Behavior of Silver(I) with Thenoyltrifluoroacetone and a Thiacrownether}, volume = {12}, year = {2005} }