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Hydration Effect on the Liquid-Liquid Distribution of Tris(8-quinolinolato)-Aluminium(III), -Gallium(III) and -Indium(III)
http://hdl.handle.net/2297/35241
http://hdl.handle.net/2297/3524140f32205-8fcf-454f-a716-55c2292a3c14
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SC-PR-IMAMURA-H-71-79.pdf (440.3 kB)
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| アイテムタイプ | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2017-10-03 | |||||
| タイトル | ||||||
| タイトル | Hydration Effect on the Liquid-Liquid Distribution of Tris(8-quinolinolato)-Aluminium(III), -Gallium(III) and -Indium(III) | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Imura, Hisanori
× Imura, Hisanori× Ozawa, Tomoyasu× Ohashi, Akira× Ohashi, Kousaburo |
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| 書誌情報 |
Solvent Extraction Research and Development, Japan 巻 15, p. 71-79, 発行日 2008-01-01 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 1341-7215 | |||||
| NCID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA11114608 | |||||
| 出版者 | ||||||
| 出版者 | Japan Association of Solvent Extraction = 日本溶媒抽出学会 | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Liquid-liquid partition coefficients of tris(8-quinolinolato)metals(III) (M(q) 3) for aluminium(III), gallium(III), and indium(III) were measured in various organic solvents at 298 K. The effect of the solvent on the partition coefficients was evaluated with the aid of a modified regular solution theory equation as well as the scaled particle theory. It was suggested that solute-water interactions for M(q) 3 are much stronger than those for 8-quinolinol (Hq) and the specific interaction with water, chloroform, and 1-octanol as the hydrogen-bond donating solvents is a dominant factor affecting the partition coefficient of M(q) 3. The hydration of M(q) 3 even in the organic phase has been evidenced by IR spectra. | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
