@article{oai:kanazawa-u.repo.nii.ac.jp:00010637, author = {松田, 駿太朗 and 森田, 耕太郎 and 平山, 直紀 and 井村, 久則}, issue = {8}, journal = {分析化学 = Analytical Sciences}, month = {Jan}, note = {Novel 8-quinolinol derivatives, 7-bromo-5-methoxymethyl-8-quinolinol (HBrO1Q) and 7-iodo-5-methoxymethyl-8-quinolinol (HIO1Q), were synthesized by halogenating 5-methoxymethyl-8- quinolinol at the 7-position. From the distribution behavior of the reagents between carbon tetrachloride and water, an increase in hydrophobicity and acidity by the halogenation was confirmed. Furthermore, a remarkable increase in the extractability of the Cu(II) ion was found. It was shown that HIO1Q had the extraction constant of Cu(II) which is the highest in 8-quinolinols reported so far.}, pages = {699--703}, title = {5-アルキルオキシメチル-8-キノリノール誘導体の銅(II)イオン抽出能に及ぼす7位ハロゲン化の効果}, volume = {61}, year = {2012} }