{"created":"2023-07-27T06:26:47.660008+00:00","id":10660,"links":{},"metadata":{"_buckets":{"deposit":"e23d47ed-f97f-4bb2-a6b6-c865992d7be5"},"_deposit":{"created_by":3,"id":"10660","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"10660"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00010660","sets":["934:935:937"]},"author_link":["16242","16243","16244","16245"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1995-02-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"166","bibliographicPageStart":"164","bibliographicVolumeNumber":"1995","bibliographic_titles":[{"bibliographic_title":"日本化学会誌 : 化学と工業化学 = Journal of the Chemical Society of Japan : chemistry and industrial chemistry"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"t is a well-known result that the reactions of t-alkyl halides with alkali metal aryl oxides and alkoxides in protic solvents give olefins (E) almost exclusively. By contrast, we found a new method for the Williamson ether synthesis in the reactions of t-alkyl halides with alkali and alkaline earth metal phenoxides and alkoxides at 60-90° C in nonpolar solvents (hexane and heptane). The yields of t-alkyl phenyl ethers and t-butyl alkyl ethers (SN) were moderate. The selectivity of SN/E was governed by solvent, metal cation (Li+, Na+, K+, Mg2+, Ca2+, Sr2+, and Ba2+), nucleophile, and substrate. The nonpolar solvents were much more effective for the SN reaction than polar solvents.","subitem_description_type":"Abstract"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本化学会 = The Chemical Society of Japan"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/nikkashi.1995.164","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.chemistry.or.jp/","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/browse/nikkashi/-char/ja/","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://ci.nii.ac.jp/naid/10001682109/","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © 日本化学会 The Chemical Society of Japan"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AN00186595","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0369-4577","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"政田, 浩光"}],"nameIdentifiers":[{"nameIdentifier":"16242","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"三口, 史雄"}],"nameIdentifiers":[{"nameIdentifier":"16243","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"土井, 靖夫"}],"nameIdentifiers":[{"nameIdentifier":"16244","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"林, 彰"}],"nameIdentifiers":[{"nameIdentifier":"16245","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"TE-PR-MASADA-H-164.pdf","filesize":[{"value":"657.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"TE-PR-MASADA-H-164.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/10660/files/TE-PR-MASADA-H-164.pdf"},"version_id":"b4ce5e6e-9aae-486a-9f98-229c3d5e29dd"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"無極性溶媒におけるハロゲン化第三級アルキルを用いた新規Williamson合成法","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"無極性溶媒におけるハロゲン化第三級アルキルを用いた新規Williamson合成法"},{"subitem_title":"A New Method for the Williamson Ether Synthesis Using t-Alkyl Halides in Nonpolar Solvents","subitem_title_language":"en"}]},"item_type_id":"4","owner":"3","path":["937"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"10660","relation_version_is_last":true,"title":["無極性溶媒におけるハロゲン化第三級アルキルを用いた新規Williamson合成法"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2024-06-20T05:57:57.409500+00:00"}