{"created":"2023-07-27T06:26:48.246910+00:00","id":10674,"links":{},"metadata":{"_buckets":{"deposit":"1dd202d2-f85f-4f21-9871-6ca9c0448c08"},"_deposit":{"created_by":3,"id":"10674","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"10674"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00010674","sets":["934:935:937"]},"author_link":["15012","108110","2072","15050","200","10605","16274","16273","1738","2877","16272"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"11","bibliographicPageEnd":"1322","bibliographicPageStart":"1309","bibliographicVolumeNumber":"83","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"木下, 英樹"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"藤波, 修平"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"宇梶, 裕"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"猪股, 勝彦"}],"nameIdentifiers":[{},{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Total syntheses of sterically locked phycocyanobilin derivatives with a 15Z-anti or a 15E-anti CD-ring component were performed toward elucidation of the stereochemistry and function of the chromophore in phytochromes. In the course of the construction of a sterically locked 15E-anti CD-ring component employing 5-tosylpyrrolin-2-one derivatives as the D-ring, the Ts group was found to be rearranged under acidic conditions to give a mixture of regioisomers, both of which could be transformed into the same CD-ring precursor via detosylation with a base followed by Wittig-like coupling reaction. In addition, a sterically locked 15E-anti biliverdin derivative was also synthesized. Total syntheses of sterically locked phycocyanobilin derivatives bearing a 15Z-anti or a 15E-anti CD-ring component were performed towards elucidation of the stereochemistry and function of the chromophore in phytochromes.","subitem_description_type":"Abstract"}]},"item_4_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00010661","subitem_identifier_reg_type":"JaLC"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Chemical Society of Japan = 日本化学会"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.20100168","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/browse/bcsj","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.chemistry.or.jp/","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © The Chemical Society of Japan 日本化学会"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA00580132","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2673","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Nishiyama, Kaori"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kamiya, Ayumi"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hammam, Mostafa A. S."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kinoshita, Hideki"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Fujinami, Shuhei"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Ukaji, Yutaka"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Inomata, Katsuhiko"}],"nameIdentifiers":[{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"SC-PR-INOMATA-K-1309.pdf","filesize":[{"value":"443.3 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-INOMATA-K-1309.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/10674/files/SC-PR-INOMATA-K-1309.pdf"},"version_id":"9be8b0f1-b898-48ab-8f95-e162aa82eb8a"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Total syntheses of sterically locked phycocyanobilin derivatives bearing a 15Z-anti or a 15E-anti CD-ring component","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Total syntheses of sterically locked phycocyanobilin derivatives bearing a 15Z-anti or a 15E-anti CD-ring component"}]},"item_type_id":"4","owner":"3","path":["937"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"10674","relation_version_is_last":true,"title":["Total syntheses of sterically locked phycocyanobilin derivatives bearing a 15Z-anti or a 15E-anti CD-ring component"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T11:28:21.712057+00:00"}