{"created":"2023-07-27T06:26:48.582304+00:00","id":10682,"links":{},"metadata":{"_buckets":{"deposit":"35eb0497-d93a-414c-99c3-a36b0fa74d7a"},"_deposit":{"created_by":3,"id":"10682","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"10682"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00010682","sets":["934:935:937"]},"author_link":["16298","15050","16297","16296"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2004-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"2229","bibliographicPageStart":"2219","bibliographicVolumeNumber":"77","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The reaction of peptides containing an N-Boc- or N-Z-α-tosylglycine residue at the N-terminus with a variety of excess nitro compounds under basic conditions to give the nitro compound-adducts in good yields, followed by the elimination of nitrous acid from the adducts to afford the corresponding dipeptide containing α,β-didehydroamino acids with (Z)-configuration predominantly. Treatment of the same starting materials with aldehydes in the presence of base and tributylphosphine also gave a dipeptide containing α,β-didehydroamino acids with high (Z)-selectivity in satisfactory yields. The present method can be successfully applied to the synthesis of a protected leucine enkephalin analog.","subitem_description_type":"Abstract"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Chemical Society of Japan = 日本化学会"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.77.2219","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/browse/bcsj","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.chemistry.or.jp/","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © The Chemical Society of Japan 日本化学会"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA00580132","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2673","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shiraishi, Yohsuke"}],"nameIdentifiers":[{"nameIdentifier":"16296","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamauchi, Hiroshi"}],"nameIdentifiers":[{"nameIdentifier":"16297","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Takamura, Takashi"}],"nameIdentifiers":[{"nameIdentifier":"16298","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kinoshita, Hideki"}],"nameIdentifiers":[{"nameIdentifier":"15050","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"20019483","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=20019483"},{"nameIdentifier":"20019483","nameIdentifierScheme":"研究者番号","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000020019483"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"SC-PR-KIOSHITA-H-2219.pdf","filesize":[{"value":"165.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"SC-PR-KIOSHITA-H-2219.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/10682/files/SC-PR-KIOSHITA-H-2219.pdf"},"version_id":"b374fc0f-3d39-4c6c-a83a-5d78cb4ebd24"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"A new synthetic method for dipeptides containing α,β- didehydroamino acids utilizing an α-tosylglycine residue","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"A new synthetic method for dipeptides containing α,β- didehydroamino acids utilizing an α-tosylglycine residue"}]},"item_type_id":"4","owner":"3","path":["937"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"10682","relation_version_is_last":true,"title":["A new synthetic method for dipeptides containing α,β- didehydroamino acids utilizing an α-tosylglycine residue"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2024-06-20T05:56:38.265108+00:00"}