{"created":"2023-07-27T06:26:50.941235+00:00","id":10739,"links":{},"metadata":{"_buckets":{"deposit":"2a4c6ef5-28af-4378-a1ac-d1bafada88cd"},"_deposit":{"created_by":3,"id":"10739","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"10739"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00010739","sets":["934:935:937"]},"author_link":["54","49959","16384","15876"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1990-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"1120","bibliographicPageStart":"1115","bibliographicVolumeNumber":"63","bibliographic_titles":[{"bibliographic_title":"Bulletin of the Chemical Society of Japan"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"鈴木, 正樹"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"上原, 章"}],"nameIdentifiers":[{},{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Two dinuclear cobalt(II,II) complexes, [Co2(tpdp)(CH3COO)](ClO4)2·0.5H2O (1) and [Co2(tmdp)(CH3COO)](ClO4)2·H2O (2), were prepared, where Htpdp and Htmdp are 1,3-bis[bis(2-pyridylmethyl)amino]-2-propanol and 1,5-bis[bis(2-pyridylmethyl)amino]-3-pentanol respectively. Their electronic spectral and magnetic data revealed that 1 and 2 are five-coordinate in the high-spin state, in the same manner as [Co2(bpmp)(CH3COO)]2+ (3) (Hbpmp=2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-methylphenol). The complexes reacted with molecular oxygen to form μ-peroxo complexes in dichloromethane and acetonitrile. The oxygen affinity of the complexes decreased in the order of 3>2>1. The relationships between the oxygen affinities and (1) the donor abilities of dinucleating ligands, (2) the energies of the charge-transfer bands (O22− to Co3+) of the μ-peroxo complexes, and (3) the redox potentials of the Co3+–O2−–Co3+/Co3+–O22−–Co3+ couple indicated that a steric effect arising from the dinucleating ligands contributes significantly to the oxygen affinities of the complexes.","subitem_description_type":"Abstract"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"The Chemical Society of Japan = 日本化学会"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1246/bcsj.63.1115","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/browse/bcsj","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.chemistry.or.jp/","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © The Chemical Society of Japan 日本化学会"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA00580132","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2673","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Suzuki, Masatatsu"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Sugisawa, Toshiharu"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Uehara, Akira"}],"nameIdentifiers":[{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"SC-PR-SUZUKI-M-1115.pdf","filesize":[{"value":"984.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"SC-PR-SUZUKI-M-1115.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/10739/files/SC-PR-SUZUKI-M-1115.pdf"},"version_id":"77f5f26f-2b6f-4cec-9108-fe5b1545b94e"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Dinuclear Cobalt(II) Complexes Containing 1,3-(or 1,5-)Bis[bis(2-pyridylmethyl)amino]-2-propanolato (or -3-pentanolato): Preparation and Reaction with Molecular Oxygen","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Dinuclear Cobalt(II) Complexes Containing 1,3-(or 1,5-)Bis[bis(2-pyridylmethyl)amino]-2-propanolato (or -3-pentanolato): Preparation and Reaction with Molecular Oxygen"}]},"item_type_id":"4","owner":"3","path":["937"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"10739","relation_version_is_last":true,"title":["Dinuclear Cobalt(II) Complexes Containing 1,3-(or 1,5-)Bis[bis(2-pyridylmethyl)amino]-2-propanolato (or -3-pentanolato): Preparation and Reaction with Molecular Oxygen"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T12:16:31.421794+00:00"}