@article{oai:kanazawa-u.repo.nii.ac.jp:00010761, author = {中野 , 武雄 and 添田, 貴宏 and 遠藤, 恆平 and 宇梶, 裕 and Kurosawa, Fumiya and Nakano, Takeo and Soeta, Takahiro and Endo, Kohei and Ukaji, Yutaka}, issue = {11}, journal = {Journal of Organic Chemistry}, month = {Jun}, note = {The stereoselective transformation of α-alkoxyacetoaldehydes to the corresponding (Z)-vinyl triflates was achieved by treatment with phenyl triflimide and DBU. The stereochemistry was explained by the "syn-effect," which was attributed primarily to an σ → π∗ interaction. The β-alkoxy vinyl triflates obtained were applied to the stereoselective synthesis of structurally diverse (Z)-allylic alcohols via transition metal-catalyzed cross-coupling reaction and [1,2]-Wittig rearrangement. © 2015 American Chemical Society.}, pages = {5696--5703}, title = {(Z)-Selective enol triflation of α-alkoxyacetoaldehydes: Application to synthesis of (Z)-allylic alcohols via cross-coupling reaction and [1,2]-wittig rearrangement}, volume = {80}, year = {2015} }