{"created":"2023-07-27T06:26:52.910931+00:00","id":10788,"links":{},"metadata":{"_buckets":{"deposit":"aa1282b7-b4cf-4501-b6c9-6b650ce2f2e8"},"_deposit":{"created_by":3,"id":"10788","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"10788"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00010788","sets":["934:935:937"]},"author_link":["306","60","16518","15608"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-04-21","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"13","bibliographicPageEnd":"7255","bibliographicPageStart":"7248","bibliographicVolumeNumber":"120","bibliographic_titles":[{"bibliographic_title":"Journal of Physical Chemistry C"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Potential-dependent adsorption behavior of meso-substituted water-soluble porphyrins at the polarized water|1,2-dichloroethane (DCE) interface was studied by polarization-modulation total internal reflection fluorescence (PM-TIRF) spectroscopy. In the PM-TIRF experiments, the fluorescence signal from the interfacial region was analyzed as a function of the periodic modulation of linear-polarizations (p and s) of the incident excitation beam. The potential-dependence of PM-TIRF responses for meso-substituted porphyrins, 5,10,15,20-tetrakis(N-methylpyridyl)porphyrin (H2TMPyP4+) and 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (H2TPPS4-), indicated that both free base porphyrins were adsorbed with relatively lying orientations at the polarized water|DCE interface. The average orientation angles (θ) were estimated as θ = 61 ± 1°for H2TMPyP4+ and θ = 65 ± 1°for H2TPPS4- with respect to the interface normal. The wavelength-dependence of polarization-modulated fluorescence signals (PM-TIRF spectrum), which corresponds to \"pure\" emission spectrum of interfacial species, clearly indicated that H2TMPyP4+ and H2TPPS4- are adsorbed with a modification of the solvation at the interface. These results demonstrated a high ability of the PM-TIRF spectroscopy for the direct characterization of fluorescent species adsorbed at polarized liquid|liquid interfaces. © 2016 American Chemical Society.","subitem_description_type":"Abstract"}]},"item_4_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Embargo Period 12 months / This article has Supplementary data","subitem_description_type":"Other"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1021/acs.jpcc.6b02178","subitem_relation_type_select":"DOI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2016 American Chemical Society"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA1217589X","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1932-7447","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Yamamoto, Sho"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nagatani, Hirohisa"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Morita, Kotaro"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"Imura, Hisanori"}],"nameIdentifiers":[{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"SC-PR-NAGATANI-H-7248_Supporting Information.pdf","filesize":[{"value":"364.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"SC-PR-NAGATANI-H-7248_Supporting Information.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/10788/files/SC-PR-NAGATANI-H-7248_Supporting Information.pdf"},"version_id":"ab540607-e2b9-4706-9562-fda9fa031470"},{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"SC-PR-NAGATANI-H-7248.pdf","filesize":[{"value":"422.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"SC-PR-NAGATANI-H-7248.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/10788/files/SC-PR-NAGATANI-H-7248.pdf"},"version_id":"8e97ec9b-0077-4927-8525-9f8472a076d9"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Potential-Dependent Adsorption and Orientation of meso-Substituted Porphyrins at Liquid|Liquid Interfaces Studied by Polarization-Modulation Total Internal Reflection Fluorescence Spectroscopy","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Potential-Dependent Adsorption and Orientation of meso-Substituted Porphyrins at Liquid|Liquid Interfaces Studied by Polarization-Modulation Total Internal Reflection Fluorescence Spectroscopy"}]},"item_type_id":"4","owner":"3","path":["937"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"10788","relation_version_is_last":true,"title":["Potential-Dependent Adsorption and Orientation of meso-Substituted Porphyrins at Liquid|Liquid Interfaces Studied by Polarization-Modulation Total Internal Reflection Fluorescence Spectroscopy"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-28T01:36:43.174120+00:00"}