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A mineral wadeite in glass, occurrence and crystal structure
http://hdl.handle.net/2297/16978
http://hdl.handle.net/2297/1697890f9a461-05de-4850-9804-a6cfd6b78a04
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
SC-PR-KIHARA-K-24.pdf (745.7 kB)
Download is available from 9999/12/31.
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||||||
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| 公開日 | 2017-11-09 | |||||||||
| タイトル | ||||||||||
| タイトル | A mineral wadeite in glass, occurrence and crystal structure | |||||||||
| 言語 | ||||||||||
| 言語 | eng | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||
| 資源タイプ | journal article | |||||||||
| 著者 |
Sakai, Kohzo
× Sakai, Kohzo× Nakagawa, Takeshi× Okuno, Masayuki× Kihara, Kuniaki |
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| 著者別表示 |
奥野, 正幸
× 奥野, 正幸
× 木原, 國昭
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| 提供者所属 | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | 金沢大学理工研究域自然システム学系 | |||||||||
| 書誌情報 |
Journal of Mineralogical and Petrological Sciences 巻 95, 号 4, p. 24-31, 発行日 2000-01-01 |
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| ISSN | ||||||||||
| 収録物識別子タイプ | ISSN | |||||||||
| 収録物識別子 | 1345-6296 | |||||||||
| NCID | ||||||||||
| 収録物識別子タイプ | NCID | |||||||||
| 収録物識別子 | AA11460926 | |||||||||
| DOI | ||||||||||
| 関連タイプ | isIdenticalTo | |||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | 10.2465/jmps.95.24 | |||||||||
| 出版者 | ||||||||||
| 出版者 | 日本岩石鉱物鉱床学会 = Japanese association of Mineralogists | |||||||||
| 抄録 | ||||||||||
| 内容記述タイプ | Abstract | |||||||||
| 内容記述 | Crystals with a hexagonal lath-like morphology were found in glass products for cathode ray tubes. These crystals are preserved at the interfaces between glass and ZrO2 ceramics in a glass melting tank. An electron microprobe analysis gives SiO2: 45.6, ZrO2: 31.5, K2O: 19.0, Na2O: 1.92, BaO: 1.46, SrO: 0.33, in wt%. These values and X-ray analyses indicated the crystals to be precipitated with the same structure as mineral wadeite, K2ZrSi3O9, whose K atom sites are partially substituted by Ba, Sr or Na atoms. The structure is hexagonal with the space group P63/m, and the unit cell dimensions of a=6.918(2) and c=10.151(3)Å. The structure was refined using X-ray diffraction intensities from a single crystal. The bond distances and angles for Si3O9 rings are well comparable with those of benitoite, BaTiSi3O9, which is another example mineral including Si3O9 rings, with slight but significant difference in non-bridging Si-O bond distances. The mean square displacements of atoms in Si3O9 rings show that the tetrahedron is rigid for Si-O bond but strongly distorted for the O-O edges of non-bridging O atoms during thermal vibrations, coordinating to Zr and K. The thermal vibrational behaviors for the non-bridging oxygen are significantly different from those in benitoite. | |||||||||
| 権利 | ||||||||||
| 権利情報 | Copyright (c) 2005 Japan Association of Mineralogical Sciences | |||||||||
| 著者版フラグ | ||||||||||
| 出版タイプ | VoR | |||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||
| 関連URI | ||||||||||
| 識別子タイプ | URI | |||||||||
| 関連識別子 | https://www.jstage.jst.go.jp/article/jmps/95/4/95_4_24/_pdf | |||||||||
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| 識別子タイプ | URI | |||||||||
| 関連識別子 | http://jams.la.coocan.jp/ | |||||||||
