@article{oai:kanazawa-u.repo.nii.ac.jp:00010893, author = {中野 , 武雄 and 添田, 貴宏 and 遠藤, 恆平 and 猪股, 勝彦 and 宇梶, 裕 and Nakano, Takeo and Soeta, Takahiro and Endo, Kohei and Inomata, Katsuhiko and Ukaji, Yutaka}, issue = {24}, journal = {Journal of Organic Chemistry}, month = {Dec}, note = {The sequential 1,4-elimination reaction of (E)-4-alkoxy-2-butenyl benzoates and [1,2]-Wittig rearrangement gave (2Z,4E)-2,4-pentadien-1-ols stereoselectively. Z-Selective formation of intermediary vinyl ethers, whose stereochemistry was well elucidated by the "syn-effect", was achieved by treatment of the 2-butenyl benzoates with KOH in the presence of Pd catalyst. The subsequent [1,2]-Wittg rearrangement by use of n-BuLi proceeded with retention of the stereochemistry of the intermediary vinyl ethers. © 2013 American Chemical Society.}, pages = {12654--12661}, title = {Stereoselective synthesis of (2 Z,4 E)-2,4-pentadien-1-ols via sequential 1,4-elimination reaction and [1,2]-wittig rearrangement starting from (E)-4-alkoxy-2-butenyl benzoates}, volume = {78}, year = {2013} }