{"created":"2023-07-27T06:26:59.253862+00:00","id":10940,"links":{},"metadata":{"_buckets":{"deposit":"7bf03420-2ec6-4c60-8381-e7f53fb64aa7"},"_deposit":{"created_by":3,"id":"10940","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"10940"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00010940","sets":["934:935:937"]},"author_link":["2072","15012","2877","200"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-06-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"187","bibliographicPageStart":"173","bibliographicVolumeNumber":"10","bibliographic_titles":[{"bibliographic_title":"Chemical Record"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"宇梶, 裕"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"猪股, 勝彦"}],"nameIdentifiers":[{},{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In order to develop a practical method for the construction of chiral molecules, we have designed a novel chiral reaction system possessing multi-metal centers utilizing tartaric acid ester as a chiral auxiliary. Based on this concept, we have developed an asymmetric 1,3-dipolar cycloaddition reaction of azomethine imines, an asymmetric hetero Diels-Alder reaction of nitroso compounds, an asymmetric Diels-Alder reaction of o-quinodimethanes. Furthermore, an asymmetric nucleophilic addition of alkynylzinc reagents, prepared in situ from dialkylzinc and 1-alkynes, to nitrones was achieved with high level of stereocontrol. In the last case, the addition of methylzinc salt of a product-like racemic hydroxylamine was found to be effective for unprecedented enhancement of enantioselectivity. © 2010 The Japan Chemical Journal Forum and Wiley Periodicals, Inc.","subitem_description_type":"Abstract"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_4_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00010927","subitem_identifier_reg_type":"JaLC"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley-Blackwell"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/tcr.201000002","subitem_relation_type_select":"DOI"}}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA11515019","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1527-8999","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ukaji, Yutaka"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Inomata, Katsuhiko"}],"nameIdentifiers":[{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"SC-PR-UKAJI-Y-173.pdf","filesize":[{"value":"190.4 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-UKAJI-Y-173.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/10940/files/SC-PR-UKAJI-Y-173.pdf"},"version_id":"338b153c-02f3-4568-a7bf-5c18035fc14a"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Recent progress in a chiral multinucleating system utilizing tartaric acid esters","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Recent progress in a chiral multinucleating system utilizing tartaric acid esters"}]},"item_type_id":"4","owner":"3","path":["937"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"10940","relation_version_is_last":true,"title":["Recent progress in a chiral multinucleating system utilizing tartaric acid esters"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T11:12:47.180077+00:00"}