{"created":"2023-07-27T06:26:59.421933+00:00","id":10944,"links":{},"metadata":{"_buckets":{"deposit":"23fef532-a64b-41d6-bec9-a778ac7f8d4a"},"_deposit":{"created_by":3,"id":"10944","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"10944"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00010944","sets":["934:935:937"]},"author_link":["16856","15012","2072","16857","1738","10605","16858","2877","200"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-11-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"1300","bibliographicPageStart":"1285","bibliographicVolumeNumber":"76","bibliographic_titles":[{"bibliographic_title":"Heterocycles"}]}]},"item_4_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"藤波, 修平"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"宇梶, 裕"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"猪股, 勝彦"}],"nameIdentifiers":[{},{}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The regio- and enantioselective hetero Diels-Alder reaction of a nitroso compound with a cyclic dienol, cyclohexa-1,3-dienylmethanol, has been realized utilizing stoichiometric amount of tartaric acid ester as a chiral auxiliary to afford the corresponding dihydro-1,2-oxazine with complete regioselectivity and high enantioselectivity of up to 92% ee. A catalytic version of the asymmetric hetero Diels-Alder reaction of nitroso compounds with the dienol was also achieved to afford the corresponding optically active cycloadducts with up to 83% ee. The addition of MS 4A was crucial to realize reproducible high enantioselectivity. © 2008 The Japan Institute of Heterocyclic Chemistry All rights reserved.","subitem_description_type":"Abstract"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_4_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00010931","subitem_identifier_reg_type":"JaLC"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本複素環化学研究所 = The Japan Institute of Heterocyclic Chemistry"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.3987/COM-08-S(N)94","subitem_relation_type_select":"DOI"}}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA00663739","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0385-5414","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sakai, Hiroki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Ding, Xia"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yoshida, Tetsusuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fujinami, Shuhei"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Ukaji, Yutaka"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Inomata, Katsuhiko"}],"nameIdentifiers":[{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"SC-PR-INOMATA-K-1285.pdf","filesize":[{"value":"247.8 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-INOMATA-K-1285.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/10944/files/SC-PR-INOMATA-K-1285.pdf"},"version_id":"906c3777-2cdf-4844-becf-65840015f6f1"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Asymmetric hetero diels-alder reaction of nitroso compounds utilizing tartaric acid ester as a chiral auxiliary","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Asymmetric hetero diels-alder reaction of nitroso compounds utilizing tartaric acid ester as a chiral auxiliary"}]},"item_type_id":"4","owner":"3","path":["937"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"10944","relation_version_is_last":true,"title":["Asymmetric hetero diels-alder reaction of nitroso compounds utilizing tartaric acid ester as a chiral auxiliary"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T11:28:26.696627+00:00"}