{"created":"2023-07-27T06:26:59.463897+00:00","id":10945,"links":{},"metadata":{"_buckets":{"deposit":"99517edf-9e0d-48d7-a6f9-7752cc8223e8"},"_deposit":{"created_by":3,"id":"10945","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"10945"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00010945","sets":["934:935:937"]},"author_link":["16862","16861","15633","15632","16860","16859"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-11-26","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"34","bibliographicPageEnd":"5258","bibliographicPageStart":"5253","bibliographic_titles":[{"bibliographic_title":"European Journal of Inorganic Chemistry"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"An all-inorganic complex, [Mn2{(CVO3) 5}2]6- (1), was synthesized, and the structure determination reveals a dinuclear manganese complex coordinated by two cyclic pentavanadate ligands. The cyclic pentavanadate units sandwich the edge-sharing octahedral dimanganese core through, coordination of the oxido group of the pentavanadate. A. dinuclear cobalt complex with, a cyclic decavanadate, [Co 2(OH2)2(VO3)10]6- (2), was also synthesized. The structure analysis reveals a dinuclear cobalt complex with a macrocyclic decavanadate, which is composed of 10 VO4 units joined by the vertex. Sharings. The CoO6 octahedrons are edge-shared, with each cobalt octahedron coordinated to five oxido groups from the decavanadate. The remaining site is occupied by - water. The coordinated water molecules are supported with hydrogen bonds in two directions. Complex 2 in acetonitrile shows no reactivity with dioxygen even at low temperature, and the cyclic voltammogram of 2 shows no redox chemistry in acetonitrile. Complex 2 exhibits chromism by water exposure both, in the solid state and. in acetonitrile. Complex 2 is green-yellow in color, and. the addition of water causes the complex to turn brown. After heating the sample, it returns to its original color in a reversible manner. The EXAFS data in acetonitrile is also reported, and is consistent with the solid-state structure. © Wiley-VCH Verlag GmbH & Co. KGaA.","subitem_description_type":"Abstract"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley-Blackwell"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/ejic.200900609","subitem_relation_type_select":"DOI"}}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA11181707","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1434-1948","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Inami, Shinnosuke"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nishio, Masaki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hayashi, Yoshihito"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"Isobe, Kiyoshi"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Kameda, Hiroyuki"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shimoda, Tatsuya"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"SC-PR-HAYASHI-Y-5253.pdf","filesize":[{"value":"601.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"SC-PR-HAYASHI-Y-5253.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/10945/files/SC-PR-HAYASHI-Y-5253.pdf"},"version_id":"ca6ad0cd-1536-44d0-8626-5c157f027958"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Dinuclear manganese and cobalt complexes with cyclic polyoxovanadate ligands: Synthesis and characterization of [Mn2V10O 30]6- and [Co2(H2O) 2V10O30]6-","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Dinuclear manganese and cobalt complexes with cyclic polyoxovanadate ligands: Synthesis and characterization of [Mn2V10O 30]6- and [Co2(H2O) 2V10O30]6-"}]},"item_type_id":"4","owner":"3","path":["937"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"10945","relation_version_is_last":true,"title":["Dinuclear manganese and cobalt complexes with cyclic polyoxovanadate ligands: Synthesis and characterization of [Mn2V10O 30]6- and [Co2(H2O) 2V10O30]6-"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-28T01:34:47.660914+00:00"}