{"created":"2023-07-27T06:27:00.760928+00:00","id":10977,"links":{},"metadata":{"_buckets":{"deposit":"53991f68-c6f4-4eff-81fe-82f25602abfc"},"_deposit":{"created_by":3,"id":"10977","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"10977"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00010977","sets":["934:935:937"]},"author_link":["16942","16941","359","15140"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2003-03-05","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"163","bibliographicPageStart":"157","bibliographicVolumeNumber":"52","bibliographic_titles":[{"bibliographic_title":"分析化学=Bunseki Kagaku"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A method using the 2H-NMR spectra was shown to be useful to study the solid state physics in diamagnetic and paramagnetic compounds and in crystals having a modulated structure. The spectra and T1 of NMR in solids were measured for [M(H2O)6][AB6] crystals to investigate the static and dynamic structure of H2O and [M(H2O)6]2+ as well as the dynamics of the electron spin in the paramagnetic M2+ ion. The physical properties of [M(H2O)6] [AB6] were found to be as follows: (1) The spin-lattice relaxations of the electron spin of M2+ in [M(H2O)6] [SiF6] (M2+ = Fe 2+ , Co2+ , Ni2+) are dominated by the Orbach process, the Orbach process, and the Raman process, respectively. The spin-lattice relaxation of the electron spin of Cu2+ in [Cu(H 2O)6][PtCl6] is caused by jumping between the Jahn-Teller configurations. (2) In [Cu(H2O)6] [PtCl 6], H2O and [Cu(H2O)6]2+ undergo 180° flips and jumping between the different Jahn-Teller configurations, respectively. A weakening of the hydrogen bond O-H⋯Cl upon deuteration results in a lowering of the transition temperature. (3) In [M(H2O)6][SiF6], H2O and [M(H 2O)6]2+ undergo 180° flips and reorientation about the C3, axis, respectively. The order-disorder transition is closely related to a freezing of this reorientation. (4) By elongation of [M(H2O)6]2+ along the C 3 axis, the mobility becomes higher. (5) The disorder of [Fe(H 2O)6]2+ in the high-temperature phase of [Fe(H2O)6][SiF6] is dynamic. Rotational modulation of [Mg(H2O)6]2+ along the C 3 axis exists in the incommensurate phase of [Mg(H2O) 6] [SiF6].","subitem_description_type":"Abstract"}]},"item_4_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学大学院自然科学研究科物質情報解析","subitem_description_type":"Other"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本分析化学会"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.2116/bunsekikagaku.52.157","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.2116/bunsekikagaku.52.157","subitem_relation_type_select":"DOI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://prb.aps.org/","subitem_relation_type_select":"URI"}}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AN00222633","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0525-1931","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"飯島, 隆広"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"水野, 元博"}],"nameIdentifiers":[{},{},{},{}]},{"creatorNames":[{"creatorName":"須原, 正彦"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"遠藤, 一央"}],"nameIdentifiers":[{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"SC-PR-ENDO-K-157.pdf","filesize":[{"value":"450.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"SC-PR-ENDO-K-157.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/10977/files/SC-PR-ENDO-K-157.pdf"},"version_id":"bf73d297-b943-4a01-9262-8f90e63d39c7"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"固体NMR法による[M(H_2O)_6][AB_6]結晶における分子及び電子スピンのダイナミクスの研究　","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"固体NMR法による[M(H_2O)_6][AB_6]結晶における分子及び電子スピンのダイナミクスの研究　"},{"subitem_title":"Molecular and electron-spin dynamics in [M(H2O)6] [AB6] as studied by solid state NMR","subitem_title_language":"en"}]},"item_type_id":"4","owner":"3","path":["937"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"10977","relation_version_is_last":true,"title":["固体NMR法による[M(H_2O)_6][AB_6]結晶における分子及び電子スピンのダイナミクスの研究　"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-28T01:34:22.740030+00:00"}