@article{oai:kanazawa-u.repo.nii.ac.jp:00011030,
 author = {Domae, Kyosuke and Uchimura, Daisuke and Koyama, Yuuki and Inami, Shinnosuke and Hayashi, Yoshihito and Isobe, Kiyoshi and Kameda, Hiroyuki and Shimoda, Tatsuya},
 issue = {7},
 journal = {Pure and Applied Chemistry},
 month = {Jan},
 note = {A new route to an alkoxohexavanadate species leads to the isolation of a bowl-type dodecavanadate without a guest molecule in the cavity. The 1D tetravanadate, [V4O11]2-, is a good precursor for the alkoxohexavanadate, [V6O13(OCH3)6]2-, which is then utilized for the [V6 + V6] coupling reaction to form the dodecavanadate, [V12O42]4-, with a capped dichloromethane molecule at the cavity entrance. We also obtained structural information on a newly discovered octadecavanadate, [V18O46(NO3)]5-, in both the solid and solution states through extended X-ray absorption fine structure (EXAFS) studies. The existence of the chiral inorganic species in acetonitrile with double-stranded V8 chains was confirmed through EXAFS oscillations. © 2009 IUPAC., 金沢大学理工研究域物質化学系},
 pages = {1323--1330},
 title = {Synthesis of a bowl-type dodecavanadate by the coupling reaction of alkoxohexavanadate and discovery of a chiral octadecavanadate},
 volume = {81},
 year = {2009}
}