@article{oai:kanazawa-u.repo.nii.ac.jp:00011838, author = {Ishida, Shinichiro and 石田, 真一郎}, issue = {3}, journal = {金沢大学工学部紀要 = Memoirs of the Faculty of Technology Kanazawa University}, month = {Jun}, note = {The mechanism of the reaction of phenyl urea with formaldehyde in dioxane­water (4: 1) in the presence of sodium hydroxide has been studied from the view­point of the reaction rates and the diffusivities. The experimental reaction rate can be represented as follows R= ₋ d〔F〕/dt = k〔C₆H₅NHCONH₂]².⁶〔NaOH〕².¹ From these results, we speculated that the mechanism of this reaction is uni molecular electrophilic substitution named S ᴇ 1. The diffusion coefficients of phenylurea and formaldehyde increase with each concentration in a lower range, which may be explained with the mechanism concluded from the experimental results of the reaction rate.}, pages = {58--61}, title = {フェニル尿素とホルムアルデヒドとの反応に関する研究}, volume = {3}, year = {1964} }