{"created":"2023-07-27T06:27:36.889932+00:00","id":11838,"links":{},"metadata":{"_buckets":{"deposit":"d237ecae-316d-440c-9201-cc536c34aff6"},"_deposit":{"created_by":3,"id":"11838","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"11838"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00011838","sets":["934:941:1024:1038"]},"author_link":["18513","18308"],"item_7_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1964-06-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"61","bibliographicPageStart":"58","bibliographicVolumeNumber":"3","bibliographic_titles":[{"bibliographic_title":"金沢大学工学部紀要 = Memoirs of the Faculty of Technology Kanazawa University"}]}]},"item_7_creator_34":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ishida, Shinichiro"}],"nameIdentifiers":[{},{}]}]},"item_7_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The mechanism of the reaction of phenyl urea with formaldehyde in dioxane­water (4: 1) in the presence of sodium hydroxide has been studied from the view­point of the reaction rates and the diffusivities. \nThe experimental reaction rate can be represented as follows\nR= ₋ d〔F〕/dt = k〔C₆H₅NHCONH₂]².⁶〔NaOH〕².¹\nFrom these results, we speculated that the mechanism of this reaction is uni molecular electrophilic substitution named S ᴇ 1. \nThe diffusion coefficients of phenylurea and formaldehyde increase with each concentration in a lower range, which may be explained with the mechanism concluded from the experimental results of the reaction rate. ","subitem_description_type":"Abstract"}]},"item_7_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00011825","subitem_identifier_reg_type":"JaLC"}]},"item_7_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"金沢大学工学部 = Faculty of Technology Kanazawa University"}]},"item_7_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AN00044309","subitem_source_identifier_type":"NCID"}]},"item_7_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0022-832X","subitem_source_identifier_type":"ISSN"}]},"item_7_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"石田, 真一郎"}],"nameIdentifiers":[{"nameIdentifier":"18308","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"40019716","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=40019716"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"AN00044309-3-3-58.pdf","filesize":[{"value":"87.4 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"AN00044309-3-3-58.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/11838/files/AN00044309-3-3-58.pdf"},"version_id":"38a628bd-5293-49b8-92e5-387619998959"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"フェニル尿素とホルムアルデヒドとの反応に関する研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"フェニル尿素とホルムアルデヒドとの反応に関する研究"},{"subitem_title":"Studies on the Reaction of Phenylurea with Formaldehyde","subitem_title_language":"en"}]},"item_type_id":"7","owner":"3","path":["1038"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"11838","relation_version_is_last":true,"title":["フェニル尿素とホルムアルデヒドとの反応に関する研究"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T09:03:50.153735+00:00"}