@article{oai:kanazawa-u.repo.nii.ac.jp:00014779, author = {Fujii, Tozo and Ohba, Masashi and Tachinami, Tsuyoshi and Miyajima, Hisae}, issue = {5}, journal = {Chemical & pharmaceutical bulletin}, month = {May}, note = {The first total synthesis of ochropposinine (1), a Neisosperma and Ochrosia alkaloid, has been accomplished in the form of a racemic modification by means of an initial coupling of the lactim ether (±)-3 with 5 and succeeding steps proceeding through the intermediates (±)-7,(±)-8,(±)-9,(±)-10,and (±)-11. A parallel synthetic route starting with (+)-3 produced the chiral target molecule (-)-1 via the intermediates (+)-7,(+)-8,(+)-9,10,and (-)-11. As a result, the absolute configuration of ochropposinine has been unequivocally established to be that represented by formula (-)-1.}, pages = {1200--1204}, title = {Quinolizidines. XXVII. Racemic and chiral syntheses of the Neisosperma and Ochrosia alkaloid ochropposinine}, volume = {38}, year = {1990} }