@article{oai:kanazawa-u.repo.nii.ac.jp:00014857, author = {Fujii, Tozo and Ohba, Masashi}, issue = {7}, journal = {Chemical & pharmaceutical bulletin}, month = {Jul}, note = {8-Hydroxyprotoemetine [(-)-2f], an aldehyde of biogenetic interest, has been synthesized for the first time from the tricyclic ester (-)-5 through the intermediate (-)-6. Wolff-Kishner reduction of (-)-2f produced the 2-ethyl congener (-)-2g. As a result of these syntheses, the circular dichroism (CD) spectra of (-)-2f・HClO_4 and (-)-2g in 0.1 N aqueous HCl and in EtOH, together with those of the Alangium alkaloids ankorine (2d) and alancine (2e), are now availale.}, pages = {2665--2668}, title = {Quinolizidines. XXIV. : Syntheses of Ankorine Congeners in Different Oxidation States}, volume = {36}, year = {1988} }