{"created":"2023-07-27T06:30:01.284753+00:00","id":14866,"links":{},"metadata":{"_buckets":{"deposit":"72c765c7-e9bc-470d-a6f8-475668f9198b"},"_deposit":{"created_by":3,"id":"14866","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"14866"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00014866","sets":["1132:1133:1135"]},"author_link":["26668","26369","26669"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1985-09-25","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"9","bibliographicPageEnd":"3730","bibliographicPageStart":"3724","bibliographicVolumeNumber":"33","bibliographic_titles":[{"bibliographic_title":"Chemical & pharmaceutical bulletin"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The first total synthesis of the Alangium vitiense alkaloid 9-demethyltubulosine (1) has been achieved in the form of a racemic modification through a\"lactim ether route, \" which included the intermediates (±)-7,(±)-8,(±)-10,and (±)-9. The 1'α-Hisomers (±)-12 and (±)-11 were also produced through this synthetic route. On the other hand, the nonconformity of synthetic (±)-1 with another (-)-demethyltubulosine from A. lamarckii indicated the alternative 10-demethyl structure (2) to be correct for the A. lamarckii alkaloid. The assignments of the configuration at C-1' of (±)-1,(±)-9,(±)-11,and (±)-12 were based on four criteria, namely, the ratio of products from the catalytic reduction of (±)-10,thin-layer chromatographic mobility, and ^1H and ^<13>C nuclear magnetic resonance spectral features.","subitem_description_type":"Abstract"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本薬学会"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1248/cpb.33.3724","subitem_relation_type_select":"DOI"}}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA00602100","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2363","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ohba, Masashi"}],"nameIdentifiers":[{"nameIdentifier":"26369","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"60115219","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=60115219"},{"nameIdentifier":"60115219","nameIdentifierScheme":"研究者番号","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000060115219"}]},{"creatorNames":[{"creatorName":"Hayashi, Mitsuko"}],"nameIdentifiers":[{"nameIdentifier":"26668","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Fujii, Tozo"}],"nameIdentifiers":[{"nameIdentifier":"26669","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"PH-PR-OHBA-M-3724.pdf","filesize":[{"value":"821.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"PH-PR-OHBA-M-3724.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/14866/files/PH-PR-OHBA-M-3724.pdf"},"version_id":"915d1da1-5229-47bf-9b50-372df255d443"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Quinolizidines. XIV. A racemic synthesis of 9-demethyltubulosine, an alkaloid isolated from Alangium vitiense","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Quinolizidines. XIV. A racemic synthesis of 9-demethyltubulosine, an alkaloid isolated from Alangium vitiense"}]},"item_type_id":"4","owner":"3","path":["1135"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"14866","relation_version_is_last":true,"title":["Quinolizidines. XIV. A racemic synthesis of 9-demethyltubulosine, an alkaloid isolated from Alangium vitiense"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2024-06-20T06:53:05.894148+00:00"}