{"created":"2023-07-27T06:30:01.583996+00:00","id":14873,"links":{},"metadata":{"_buckets":{"deposit":"c4e884ad-af04-45fc-b091-e2325f6836c6"},"_deposit":{"created_by":3,"id":"14873","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"14873"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00014873","sets":["1132:1133:1135"]},"author_link":["26369","26686","26685"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1999-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"89","bibliographicPageStart":"83","bibliographicVolumeNumber":"47","bibliographic_titles":[{"bibliographic_title":"Chemical & pharmaceutical bulletin"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A chiral synthetic route to the amino esters 5 and 6, which contain the fundamental framework of ent-imbricatine (ent-3), has been developed as a prelude to the total synthesis of the starfish alkaloid imbricatine (3). The route started from the sulfur-containing L-phenylalanine derivative 7 and proceeded through key steps such as cyclization of the amide 8 without racemization, reduction to the 1,3-cis-tetrahydroisoquinoline 9, and introduction of a chiral α-amino acid moiety into the chloride 18 by the 'bis-lactim ether' method.","subitem_description_type":"Abstract"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本薬学会"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1248/cpb.47.83","subitem_relation_type_select":"DOI"}}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA00602100","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2363","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ohba, Masashi"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Imasho, M."}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Fujii, Tozo"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"PH-PR-OHBA-M-83.pdf","filesize":[{"value":"1.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"PH-PR-OHBA-M-83.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/14873/files/PH-PR-OHBA-M-83.pdf"},"version_id":"6d847c7f-8d72-4b6f-a4f8-239c3cdd98fb"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthetic studies on the starfish alkaloid imbricatine. Construction of an ent-imbricatine framework","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthetic studies on the starfish alkaloid imbricatine. Construction of an ent-imbricatine framework"}]},"item_type_id":"4","owner":"3","path":["1135"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"14873","relation_version_is_last":true,"title":["Synthetic studies on the starfish alkaloid imbricatine. Construction of an ent-imbricatine framework"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T12:23:21.012808+00:00"}