{"created":"2023-07-27T06:30:02.714910+00:00","id":14900,"links":{},"metadata":{"_buckets":{"deposit":"6a5daf6f-c48d-45b9-9c7c-b3894242dcf9"},"_deposit":{"created_by":3,"id":"14900","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"14900"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00014900","sets":["1132:1133:1135"]},"author_link":["26369","26747","26749","26748"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1985-01-25","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"361","bibliographicPageStart":"358","bibliographicVolumeNumber":"33","bibliographic_titles":[{"bibliographic_title":"Chemical & pharmaceutical bulletin"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The resolution of (±)-trans-1-benzyl-5-ethyl-2-oxo-4-piperidineacetic acid [(±)-1] was effected with (R)-(+)-α-phenylethylamine through formation of the diastereomeric salts (+)-2 and (-)-3. Conversion of (+)-1 into the (3R, 4R)-(+)-enantiomer [(+)-6] of the title compound proceeded via a route involving debenzylation of (+)-1 with Na in liquid NH_3,esterification of the resulting (+)-4 to give (+)-5,and ethylation of (+)-5 with triethyloxonium fluoroborate. A parallel sequence of reactions starting from (-)-1 produced (-)-6 through (-)-4 and (-)-5.","subitem_description_type":"Abstract"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"日本薬学会"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1248/cpb.33.358","subitem_relation_type_select":"DOI"}}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA00602100","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2363","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Fujii, Tozo"}],"nameIdentifiers":[{"nameIdentifier":"26747","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ohba, Masashi"}],"nameIdentifiers":[{"nameIdentifier":"26369","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"60115219","nameIdentifierScheme":"e-Rad","nameIdentifierURI":"https://kaken.nii.ac.jp/ja/search/?qm=60115219"},{"nameIdentifier":"60115219","nameIdentifierScheme":"研究者番号","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000060115219"}]},{"creatorNames":[{"creatorName":"Yoneyama, Kaoru"}],"nameIdentifiers":[{"nameIdentifier":"26748","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kizu, Hiroko"}],"nameIdentifiers":[{"nameIdentifier":"26749","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-03"}],"displaytype":"detail","filename":"PH-PR-OHBA-M-358.pdf","filesize":[{"value":"622.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"PH-PR-OHBA-M-358.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/14900/files/PH-PR-OHBA-M-358.pdf"},"version_id":"45a41eac-ca1a-4d08-9572-6b4d841e98dc"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Lactams. XXII. Preparation of the Enantiomers of 6-Ethoxy-3-ethyl-2,3,4,5-tetrahydro-4-pyridineacetic Acid Ethyl Ester","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Lactams. XXII. Preparation of the Enantiomers of 6-Ethoxy-3-ethyl-2,3,4,5-tetrahydro-4-pyridineacetic Acid Ethyl Ester"}]},"item_type_id":"4","owner":"3","path":["1135"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-03"},"publish_date":"2017-10-03","publish_status":"0","recid":"14900","relation_version_is_last":true,"title":["Lactams. XXII. Preparation of the Enantiomers of 6-Ethoxy-3-ethyl-2,3,4,5-tetrahydro-4-pyridineacetic Acid Ethyl Ester"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2024-06-20T06:56:58.487660+00:00"}