{"_buckets": {"deposit": "2cca4e67-35f8-4f55-808a-a90a17c6c6f8"}, "_deposit": {"created_by": 3, "id": "14955", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "14955"}, "status": "published"}, "_oai": {"id": "oai:kanazawa-u.repo.nii.ac.jp:00014955", "sets": ["1135"]}, "author_link": ["24593", "26419", "26874", "26779"], "item_4_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2005-12-31", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "594", "bibliographicPageStart": "583", "bibliographicVolumeNumber": "66", "bibliographic_titles": [{"bibliographic_title": "Heterocycles"}]}]}, "item_4_description_21": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "1-Methoxy-3-(2-nitrovinyl)indole (1a) functions as an electrophile and reacts with various nucleophiles. In THF, nucleophiles undergo conjugate addition to the β-carbon of the nitroviyyl side chain of 1a, regioselectively. The resultant Michael addition products (4d and 8) cyclize to novel 3-substituted 1-methoxyindoles (5 and 7) depending on reaction conditions and a plausible mechanism is discussed. In dipolar aprotic solvent (DMF), nucleophiles react with 1a at the 2-position predominantly with concomitant liberation of the 1-methoxy group giving 2-substituted indoles. © 2005 The Japan Institute of Heterocyclic Chemistry.", "subitem_description_type": "Abstract"}]}, "item_4_description_5": {"attribute_name": "提供者所属", "attribute_value_mlt": [{"subitem_description": "金沢大学大学院自然科学研究科生理活性物質科学", "subitem_description_type": "Other"}, {"subitem_description": "金沢大学薬学部", "subitem_description_type": "Other"}]}, "item_4_publisher_17": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "日本複素環化学研究所"}]}, "item_4_relation_12": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isIdenticalTo", "subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.3987/com-05-s(k)33", "subitem_relation_type_select": "DOI"}}]}, "item_4_rights_23": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "日本複素環化学研究所の許諾を得て登録"}]}, "item_4_source_id_11": {"attribute_name": "NCID", "attribute_value_mlt": [{"subitem_source_identifier": "AA00663739", "subitem_source_identifier_type": "NCID"}]}, "item_4_version_type_25": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yamada, Koji"}], "nameIdentifiers": [{"nameIdentifier": "26779", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "80272962", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=80272962"}, {"nameIdentifier": "80272962", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000080272962"}]}, {"creatorNames": [{"creatorName": "Izumi, Tomoyuki"}], "nameIdentifiers": [{"nameIdentifier": "26874", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamada, Fumio"}], "nameIdentifiers": [{"nameIdentifier": "26419", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "80135087", "nameIdentifierScheme": "e-Rad", "nameIdentifierURI": "https://kaken.nii.ac.jp/ja/search/?qm=80135087"}, {"nameIdentifier": "80135087", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000080135087"}]}, {"creatorNames": [{"creatorName": "Somei, Masanori"}], "nameIdentifiers": [{"nameIdentifier": "24593", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "20110546", "nameIdentifierScheme": "研究者番号", "nameIdentifierURI": "https://nrid.nii.ac.jp/nrid/1000020110546"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-10-04"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "AA00663739-2005-583.pdf", "filesize": [{"value": "1.2 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 1200000.0, "url": {"label": "AA00663739-2005-583.pdf", "url": "https://kanazawa-u.repo.nii.ac.jp/record/14955/files/AA00663739-2005-583.pdf"}, "version_id": "3ab37676-c5ff-4e39-9406-fe6e1b74b86e"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Solvent effect on the reaction of 1-methoxy-3-(2-nitrovinyl)indole with nucleophiles", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Solvent effect on the reaction of 1-methoxy-3-(2-nitrovinyl)indole with nucleophiles"}]}, "item_type_id": "4", "owner": "3", "path": ["1135"], "permalink_uri": "http://hdl.handle.net/2297/4383", "pubdate": {"attribute_name": "公開日", "attribute_value": "2017-10-04"}, "publish_date": "2017-10-04", "publish_status": "0", "recid": "14955", "relation": {}, "relation_version_is_last": true, "title": ["Solvent effect on the reaction of 1-methoxy-3-(2-nitrovinyl)indole with nucleophiles"], "weko_shared_id": 3}