@article{oai:kanazawa-u.repo.nii.ac.jp:00015042,
 author = {岸田, 真男 and 今村, 清 and 亀田, 貴之 and 早川, 和一 and 坂東, 博},
 issue = {2},
 journal = {環境化学 = journal of environmental chemistry},
 month = {Jan},
 note = {A determination method of atmospheric oxygenated polycyclic aromatic hydrocarbons (Oxy-PAHs) in particulate matter and the gaseous phase using gas chromatograph (GC)-mass spectrometer (MS) was studied in the present study. First, we obtained fundamental data of GC-MS analyses (mass spectra and calibration curves) of twelve Oxy-PAHs as follows: acenaphthenequinone (AceQ), 1,4-naphtoquinone (1,4-NQ), 9-fluorenone (9-F-one), 1,4-phenanthrenequinone (1,4-PQ), 1,4-, 9,10-anthaquinone (1,4-, 9,10-AQ), 1-hydroxyanthrquinone (1-OHAQ), 1,2-benzanthraquinone (1,2-BAQ), benz[c]phenanthrene[1,4]quinine (BcP-1,4Q), 3,4-dihydrobenzo[a]anthracene-1(2H)-one (BaA-one), 1,4-chrysenequinone (1,4-CQ) and 9,10-dihydrobenzo[a]pyrene-7(8H)-one (BaP-one). Subsequently, to evaluate collection efficiency of Oxy-PAHs, air was passed through a quartz-fiber filter (QFF) spiked with authentic Oxy-PAHs and then through cleaned polyurethane form (PUF) plugs using a mini-pump or a low-volume air sampler for 24 h in the dark at a constant room temperature (20 or 35 °C). Oxy-PAHs retained on the QFF and those trapped within PUF plugs were simultaneously Soxhlet extracted, purified with silica by gel column chromatography and determined using GC-MS. The calibration curves for the determination of the twelve Oxy-PAHs were proportional in the concentration range between 0.02 and 1.0 μg/mL with r2 values of 0.960-0.999. Among the twelve Oxy-PAH compounds examined, recoveries of six compounds (1,4-NQ, 9-F-one, 9,10-AQ, 1,2-BAQ, BaA-one and BaP-one) during sampling, Soxhlet-extraction and clean-up procedures sufficiently yielded 79-127% at a room temperature of 20 °C and 57-127% at 35 °C . The method detection limits (MDLs) of the six compounds ranged between 0.61-1.07 ng/m3. The proposed method was applied to the determination of the six Oxy-PAH compounds in the atmosphere. Air sample was collected at an urban location of Osaka, Japan for 12-13 February 2007. 1,4-NQ, 9-F-one and 9-F-one were detected in the sample at concentration level of approximately 0.7-3 ng/m3.},
 pages = {173--181},
 title = {GC-MS を用いた大気中多環芳香族炭化水素酸化物の分析法開発に関する基礎検討},
 volume = {20},
 year = {2010}
}