{"created":"2023-07-27T06:30:13.193302+00:00","id":15148,"links":{},"metadata":{"_buckets":{"deposit":"d1e8a94b-42b2-4795-8798-a0d4d5ea3030"},"_deposit":{"created_by":3,"id":"15148","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"15148"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00015148","sets":["1132:1133:1135"]},"author_link":["27336","27331","24593","27334","27333","27332","27335","1106"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1982-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"85","bibliographicPageStart":"74","bibliographicVolumeNumber":"30","bibliographic_titles":[{"bibliographic_title":"Chemical and Pharmaceutical Bulletin"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Irradiation (≥300 nm) of methyl 2-phenyl-3, 1-benzoxazepine-5-carboxylate in an alcohol afforded the Z-isomer of methyl 3-alkoxy-2-(2-benzamidophenyl)-acrylate as the major addition product. In contrast, thermal reaction of the oxazepine with a primary alcohol in the presence of triethylamine led to the exclusive formation of the corresponding E-isomer. The same kinds of Michael addition products were also obtained stereoselectively from 3, 1-benzoxazepines having an acetyl group at the 5-position under these conditions. The interrelation between the stereoisomers obtained from the oxazepine and an alcohol under these two conditions was established by photochemical equilibration, and the stereochemistry of the two isomers was determined by proton magnetic resonance spectroscopy. An explanation is proposed for the observed stereoselectivities in the two kinds (photochemical and thermal) of reactions.","subitem_description_type":"Abstract"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Pharmaceutical Society of Japan = 日本薬学会"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1248/cpb.30.74","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/browse/cpb","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.pharm.or.jp/","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © PHARMACEUTICAL SOCIETY OF JAPAN"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA00602100","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2363","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Kaneko, Chikara"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"Fujii, Harue"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kawai, Shinji"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hashiba, Kazuhiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Karasawa, Yoshio"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Wakai, Masue"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Hayashi, Reiko"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Somei, Masanori"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-04"}],"displaytype":"detail","filename":"PH-PR-SOMEI-M-74.pdf","filesize":[{"value":"1.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"PH-PR-SOMEI-M-74.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/15148/files/PH-PR-SOMEI-M-74.pdf"},"version_id":"8901c7b7-57d3-4d3f-97b6-0c69605d32f0"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Studies on the N-Oxides of π-Deficient N-Heteroaromatics. XXXVI. Photochemical and Thermal Michael Reactions of Alcohols with Methyl 2-Phenyl-3, 1-benzoxazepine-5-carboxylate and Its Derivatives","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Studies on the N-Oxides of π-Deficient N-Heteroaromatics. XXXVI. Photochemical and Thermal Michael Reactions of Alcohols with Methyl 2-Phenyl-3, 1-benzoxazepine-5-carboxylate and Its Derivatives"}]},"item_type_id":"4","owner":"3","path":["1135"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-04"},"publish_date":"2017-10-04","publish_status":"0","recid":"15148","relation_version_is_last":true,"title":["Studies on the N-Oxides of π-Deficient N-Heteroaromatics. XXXVI. Photochemical and Thermal Michael Reactions of Alcohols with Methyl 2-Phenyl-3, 1-benzoxazepine-5-carboxylate and Its Derivatives"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-07-28T00:37:26.475146+00:00"}