{"created":"2023-07-27T06:30:13.787304+00:00","id":15162,"links":{},"metadata":{"_buckets":{"deposit":"3b9e848a-6789-48ea-b951-f4c6bd810955"},"_deposit":{"created_by":3,"id":"15162","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"15162"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00015162","sets":["1132:1133:1135"]},"author_link":["24593"],"item_4_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1986-01-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"10","bibliographicPageEnd":"4115","bibliographicPageStart":"4109","bibliographicVolumeNumber":"34","bibliographic_titles":[{"bibliographic_title":"Chemical and Pharmaceutical Bulletin"}]}]},"item_4_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Trivalent titanium ion can reduce arylaldehydes, and the reaction is controllable by selecting the pH of the reaction medium. Utilizing this new finding, 6-indolecarbaldehyde and 6-indolemethanol were convenienthy produced by the modified Leimgruber-Batcho method with titanium(III) chloride as the reducing agent. Syntheses of a natural alkaloid, (E)-6-(3-methylbuta-1, 3-dienyl)indole, and some new 6-substituted 1-hydroxyindoles are also reported.","subitem_description_type":"Abstract"}]},"item_4_publisher_17":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Pharmaceutical Society of Japan = 日本薬学会"}]},"item_4_relation_12":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1248/cpb.34.4109","subitem_relation_type_select":"DOI"}}]},"item_4_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.jstage.jst.go.jp/browse/cpb","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://www.pharm.or.jp/","subitem_relation_type_select":"URI"}}]},"item_4_rights_23":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright © PHARMACEUTICAL SOCIETY OF JAPAN"}]},"item_4_source_id_11":{"attribute_name":"NCID","attribute_value_mlt":[{"subitem_source_identifier":"AA00602100","subitem_source_identifier_type":"NCID"}]},"item_4_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0009-2363","subitem_source_identifier_type":"ISSN"}]},"item_4_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Somei, Masanori"}],"nameIdentifiers":[{"nameIdentifier":"24593","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"20110546","nameIdentifierScheme":"研究者番号","nameIdentifierURI":"https://nrid.nii.ac.jp/nrid/1000020110546"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-04"}],"displaytype":"detail","filename":"PH-PR-SOMEI-M-4109.pdf","filesize":[{"value":"815.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"PH-PR-SOMEI-M-4109.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/15162/files/PH-PR-SOMEI-M-4109.pdf"},"version_id":"f157dead-00b1-4e1f-85e6-8a218d07b484"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"The Chemistry of Indoles. XXXII. : A Facile Synthetic Method for 6-Indolecarbaldehyde, 6-Indolemethanol, and 6-Substituted 1-Hydroxyindoles and Its Application for the Synthesis of a Natural Alkaloid, (E)-6-(3-Methylbuta-1, 3-dienyl)indole","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"The Chemistry of Indoles. XXXII. : A Facile Synthetic Method for 6-Indolecarbaldehyde, 6-Indolemethanol, and 6-Substituted 1-Hydroxyindoles and Its Application for the Synthesis of a Natural Alkaloid, (E)-6-(3-Methylbuta-1, 3-dienyl)indole"}]},"item_type_id":"4","owner":"3","path":["1135"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-04"},"publish_date":"2017-10-04","publish_status":"0","recid":"15162","relation_version_is_last":true,"title":["The Chemistry of Indoles. XXXII. : A Facile Synthetic Method for 6-Indolecarbaldehyde, 6-Indolemethanol, and 6-Substituted 1-Hydroxyindoles and Its Application for the Synthesis of a Natural Alkaloid, (E)-6-(3-Methylbuta-1, 3-dienyl)indole"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2024-06-20T06:52:54.632162+00:00"}