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Photochemistry of bifunctional chain molecules containing benzophenone and anilino chromophores. Magnetic field and magnetic isotope effects on lifetimes of triplet biradicals
http://hdl.handle.net/2297/38252
http://hdl.handle.net/2297/38252784cc1f1-b86d-4644-a8a8-4f0370bb5477
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
PH-PR-NAKAGAKI-R-347.pdf (1.4 MB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2017-10-04 | |||||
| タイトル | ||||||
| タイトル | Photochemistry of bifunctional chain molecules containing benzophenone and anilino chromophores. Magnetic field and magnetic isotope effects on lifetimes of triplet biradicals | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 著者 |
Nakagaki, Ryoichi
× Nakagaki, Ryoichi× Yamaoka, Masaharu× Mutai, Kiyoshi |
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| 書誌情報 |
Bulletin of the Chemical Society of Japan 巻 72, 号 3, p. 347-355, 発行日 1999-01-01 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0009-2673 | |||||
| NCID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00580132 | |||||
| DOI | ||||||
| 関連タイプ | isIdenticalTo | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | 10.1246/bcsj.72.347 | |||||
| 出版者 | ||||||
| 出版者 | The Chemical Society of Japan = 日本化学会 | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The decay time of biradicals containing a benzophenone ketyl and an anilino-alkyl radical has been examined by nano-second laser photolysis in the presence of external magnetic fields up to 1 T. When sites with high spin densities are labeled with heavy carbon, noticeable magnetic isotope effects are observed on the decay kinetics for biradicals. Small kinetic effects are observed for deuterated species. The obtained results can be interpreted in terms of spin-lattice relaxation due to anisotropic hyperfine and dipole–dipole interactions. Procedures for preparing labeled species are also described. | |||||
| 権利 | ||||||
| 権利情報 | Copyright © The Chemical Society of Japan 日本化学会 | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 関連URI | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | https://www.jstage.jst.go.jp/browse/bcsj | |||||
| 関連URI | ||||||
| 識別子タイプ | URI | |||||
| 関連識別子 | http://www.chemistry.or.jp/ | |||||
