{"created":"2023-07-27T06:44:23.662863+00:00","id":34601,"links":{},"metadata":{"_buckets":{"deposit":"6ce25090-9904-4fae-89d8-8cdcf22d88bd"},"_deposit":{"created_by":3,"id":"34601","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"34601"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00034601","sets":["2812:2813:2822"]},"author_link":["200"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012-05-14","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"6p.","bibliographicVolumeNumber":"2009-2011","bibliographic_titles":[{"bibliographic_title":"平成23(2011)年度 科学研究費補助金 基盤研究(C) 研究成果報告書"},{"bibliographic_title":"2011 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{},{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"1, 3-双極子は,複素環化合物合成における有用な合成素子であるにもかかわらず,効率的立体制御法は未確立であった。本研究では,「キラル環境にある金属複数による1, 3-双極子の高次立体制御」というコンセプトに基づき種々検討した結果,アゾメチンイミンの協奏的不斉1, 3-双極子付加環化反応,ニトロンへのアセチリドの求核付加を基盤とする環化骨格変換反応等の新規開発により各種光学活性複素環の高効率的合成法を実現することができた。","subitem_description_type":"Abstract"},{"subitem_description":"Based on our concept of a novel chiral reaction system possessing multi-metal centers utilizing tartaric acid ester as a chiral auxiliary, a series of concerted asymmetric 1, 3-dipolar cycloaddition of azomethine imines and asymmetric nucleophilic addition of acetylides to nitrones followed by cyclization and rearrangement were developed to afford various types of optically active heterocycles.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"出典：研究課題「1, 3-双極子の高次立体制御法の開発と光学活性複素環化合物合成への応用」課題番号21550038\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所）） \n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-21550038/21550038seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00034588","subitem_identifier_reg_type":"JaLC"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=80193853","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21550038/","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-21550038/21550038seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-05"}],"displaytype":"detail","filename":"SC-PR-UKAJI-Y-kaken 2012-6p.pdf","filesize":[{"value":"241.1 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-UKAJI-Y-kaken 2012-6p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/34601/files/SC-PR-UKAJI-Y-kaken 2012-6p.pdf"},"version_id":"778c3cd3-149d-43a7-b133-f7803c99bdde"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"1, 3-双極子の高次立体制御法の開発と光学活性複素環化合物合成への応用","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"1, 3-双極子の高次立体制御法の開発と光学活性複素環化合物合成への応用"},{"subitem_title":"Highly Efficient Stereocontrol of 1,3-Dipoles and Its Synthetic Application to Chiral Heterocycles","subitem_title_language":"en"}]},"item_type_id":"9","owner":"3","path":["2822"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-05"},"publish_date":"2017-10-05","publish_status":"0","recid":"34601","relation_version_is_last":true,"title":["1, 3-双極子の高次立体制御法の開発と光学活性複素環化合物合成への応用"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T13:29:54.249986+00:00"}