{"created":"2023-07-27T06:44:33.604169+00:00","id":34828,"links":{},"metadata":{"_buckets":{"deposit":"2eff6770-5cf4-4ef0-a9c3-9ec5aa55bd3b"},"_deposit":{"created_by":3,"id":"34828","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"34828"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00034828","sets":["2812:2813:2833"]},"author_link":["35"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2001-03-01","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"10p.","bibliographicVolumeNumber":"1998-2000","bibliographic_titles":[{"bibliographic_title":"平成12(2000)年度 科学研究費補助金 基盤研究(B) 研究成果報告書"},{"bibliographic_title":"2000 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"1.自動ニトロアレーン(NPAH)分析計の開発:これまでの基礎検討結果に基づいて,化学発光検出HPLCにクリーンアップカラム,Pt/Rhカラム及び濃縮カラム装着流路切換えバルブを導入した自動NPAH分析システムを完成した.これにより,大気浮遊粉塵のベンゼン/エタノール抽出物中の1,3-,1,6-,1,8-ジニトロピレン(DNP)及び1-ニトロピレン(NP)等を簡単な前処理で連続定量分析可能とした.2.金沢,富山及びウラジオストクの都市大気中NPAHの比較:3都市の大気粉塵を季節毎に同時連続捕集しNPAH分析した結果,1,3-,1,6-,1,8-DNP,1-NPは,金沢と同様に他の2都市とも冬高夏低を呈し,主要排出源は自動車であった.2-NPは金沢と同様に他の2都市とも夏高冬低を呈し,大気中二次生成することがわかった.更に,これまで挙動が不明であった6-ニトロクリセン,6-ニトロベンツ[a]アントラセン,7-ニトロベンゾ[a]ピレンについて金沢の大気で解析した結果,多交通量地点では冬高夏低,少交通量地点ではこれと異なる季節変動を呈することを明らかにした.また,これまで実態が不明だったウラジオストクは高濃度で,NPAHと推定される多成分が観察されることから,自動車以外の寄与も大きいと推定された.3.単気筒ディーゼル機関の運転条件とDEP排出特性:異なる負荷条件,燃焼効率で運転したディーゼル内燃機関からのDEPをソックスレー抽出して可溶性画分(SOF)を得て,多環芳香族炭化水素(PAH),NPAHを分析した結果,DEP排出量とSOF/DEP比,PAHとNPAHの排出量,直接変異原性のいずれも負荷に依存して増加することを明らかにした.軽油にジメチルカルボネート5%を添加しても,これらの値に顕著な変化は見られなかった.4.DEPの内分泌撹乱作用:ヒト培養細胞を用いて調べた結果,DEP抽出物に抗エストロゲン作用並びに抗アンドロゲン作用があり,それらの作用の一部はPAHに由来することを発見した.","subitem_description_type":"Abstract"},{"subitem_description":"(1)A clean-up column, a Pt/Rh reducer column and a switching valve with a concentrator column were introduced into the previous HPLC system equipped with a chemiluminescence detector. The proposed system determined trace levels of nitroarenes(NPAHs)in benzene-ethanol extracts from airborne particulates after simple treatments.\n(2)Airborne particulates were collected in Kanazawa, Toyama and Vladivostok(Russia), every season simultaneously. Atmospheric concentrations of 1-nitropyrene(NP), 1,3-, 1,6-and 1,8-dinitropyrenes(DNPs)showed seasonal variation(higher in winter than in summer)and automobiles were considered as the main contributor. 2-NP showed the different variation(higher in summer than in winter), suggesting the atmospheric formation. The atmospheric behaviors of 6-nitrochrysene, 7-nitrobenz[a]anthracene and 6-nitrobenzo[a]pyrene have been revealed. The results suggested that not only automobiles but also other contributors were also important in Vladivostok.\n(3)Amounts of particulates exhausted from diesel-engine increased with the increase in loading. Amounts of organic-soluble fraction of particulate, polycyclic aromatic hydrocarbons(PAHs), NPAHs and direct-acting mutagenicity were also increased with the increase in loading. Analytical results of both NPAHs and PAHs did not show the effect of the addition of dimethyl carboxylate to light oil.\n(4)The extracts from diesel exhaust particulates showed antiestrogenic activities in estrogen-responsive MCF-7 cells and antiandrogenic activities in androgen-responsive PC-3/AR cells. We found that a part of these activities were attributed to PAHs in the extracts.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:10557215, 研究期間(年度):1998–2000","subitem_description_type":"Other"},{"subitem_description":"出典：「ディーゼル排気粉塵由来未規制有害大気汚染物質の低減化に関する研究」研究成果報告書　課題番号10557215\n(KAKEN：科学研究費助成事業データベース（国立情報学研究所）)\n　　　本文データは著者版報告書より作成","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00034815","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学薬学部"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=40115267","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-10557215/","subitem_relation_type_select":"URI"}},{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-10557215/105572152000kenkyu_seika_hokoku_gaiyo/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-10-05"}],"displaytype":"detail","filename":"PH-PR-HAYAKAWA-K-kaken 2001-10p.pdf","filesize":[{"value":"565.8 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"PH-PR-HAYAKAWA-K-kaken 2001-10p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/34828/files/PH-PR-HAYAKAWA-K-kaken 2001-10p.pdf"},"version_id":"7fc20d9f-0586-4c17-8cf9-b512eb6f4f17"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"ディーゼル排気粉塵由来未規制有害大気汚染物質の低減化に関する研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ディーゼル排気粉塵由来未規制有害大気汚染物質の低減化に関する研究"},{"subitem_title":"Studies on Reduction of Unregulated Air Pollutants Exhausted from Diesel Engine Vehicles","subitem_title_language":"en"}]},"item_type_id":"9","owner":"3","path":["2833"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-10-05"},"publish_date":"2017-10-05","publish_status":"0","recid":"34828","relation_version_is_last":true,"title":["ディーゼル排気粉塵由来未規制有害大気汚染物質の低減化に関する研究"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-07-27T14:46:12.033288+00:00"}