{"created":"2023-07-27T06:50:17.924800+00:00","id":43024,"links":{},"metadata":{"_buckets":{"deposit":"ab6efb5a-ad0f-46a6-a0ab-31a09ec14979"},"_deposit":{"created_by":18,"id":"43024","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"43024"},"status":"published"},"_oai":{"id":"oai:kanazawa-u.repo.nii.ac.jp:00043024","sets":["2812:2813:2821"]},"author_link":["69217","3942"],"item_9_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013-05-20","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"5p.","bibliographicVolumeNumber":"2010-2012","bibliographic_titles":[{"bibliographic_title":"平成24(2012)年度 科学研究費補助金 基盤研究(B) 研究成果報告書"},{"bibliographic_title":"2012 Fiscal Year Final Research Report","bibliographic_titleLang":"en"}]}]},"item_9_creator_33":{"attribute_name":"著者別表示","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{}],"nameIdentifiers":[{},{}]}]},"item_9_description_21":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"本研究では,様々な酸素活性種を持つ二核(μ-η^2-η^2-peroxo)Cu(II)_2,(μ-1,2-peroxo)Fe(III)_2,bis(μ-oxo)Ni(III)_2 およびbis(μ-oxo)Co(III)_2 錯体を合成し,酸化反応性を調べた。その結果,二核錯体でCo(III)_2 錯体を除いて様々なC-H結合解離エネルギー(~80 -~92 kcal mol^-1)を持つ脂肪族化合物を水素引き抜き反応で酸化することを見いだした。","subitem_description_type":"Abstract"},{"subitem_description":"(μ-η^2:η^2-Peroxo)Cu(II)_2, (μ-1,2-peroxo)Fe(III)_2, bis(μ-oxo)Ni(III)_2, and bis(μ-oxo)Co(III)_2 complexes were prepared using dinucleating ligands. All the complexes except for (μ-oxo)Co(III)_2 complex are capable of initiating the oxidation of aliphatic C-H bonds having BDEsfrom ~80 - ~92 kcal mol^-1 by H-atom abstraction.","subitem_description_type":"Abstract"}]},"item_9_description_22":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"研究課題/領域番号:22350027, 研究期間(年度):2010-2012","subitem_description_type":"Other"},{"subitem_description":"出典：研究課題「アルカン及びアレーン酸化能を持つ二核金属錯体の創製」課題番号22350027\n（KAKEN：科学研究費助成事業データベース（国立情報学研究所））\n（https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-22350027/22350027seika/）を加工して作成","subitem_description_type":"Other"}]},"item_9_description_5":{"attribute_name":"提供者所属","attribute_value_mlt":[{"subitem_description":"金沢大学理工研究域物質化学系","subitem_description_type":"Other"}]},"item_9_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24517/00049373","subitem_identifier_reg_type":"JaLC"}]},"item_9_publisher_17":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"金沢大学物質化学系"}]},"item_9_relation_28":{"attribute_name":"関連URI","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/search/?qm=20091390"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/search/?qm=20091390","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22350027/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-22350027/","subitem_relation_type_select":"URI"}},{"subitem_relation_name":[{"subitem_relation_name_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-22350027/22350027seika/"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://kaken.nii.ac.jp/report/KAKENHI-PROJECT-22350027/22350027seika/","subitem_relation_type_select":"URI"}}]},"item_9_version_type_25":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-12-11"}],"displaytype":"detail","filename":"SC-PR-SUZUKI-M-kaken 2013-5p.pdf","filesize":[{"value":"565.6 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"SC-PR-SUZUKI-M-kaken 2013-5p.pdf","url":"https://kanazawa-u.repo.nii.ac.jp/record/43024/files/SC-PR-SUZUKI-M-kaken 2013-5p.pdf"},"version_id":"30503684-3f86-4fea-bf72-93a6dbde814d"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"アルカン及びアレーン酸化能を持つ二核金属錯体の創製","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"アルカン及びアレーン酸化能を持つ二核金属錯体の創製"},{"subitem_title":"Syntheses of Dimetal Complexes Capable of Oxidizing Alkanes and Arenes","subitem_title_language":"en"}]},"item_type_id":"9","owner":"18","path":["2821"],"pubdate":{"attribute_name":"公開日","attribute_value":"2017-12-11"},"publish_date":"2017-12-11","publish_status":"0","recid":"43024","relation_version_is_last":true,"title":["アルカン及びアレーン酸化能を持つ二核金属錯体の創製"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-07-27T12:42:52.937508+00:00"}